Limestone Conversion to Cement Clinker Precursor in a Zero-Gap Electrolyzer.

The carbon intensity of industrial cement production could be reduced by replacing the high-temperature kilns used to decompose limestone (CaCO). One possible solution is to use electrochemical reactors to convert CaCO into Ca(OH). The challenge is that most continuous-flow electrochemical reactors reported to date require voltages that are too high (>4 V at 100 mA cm) to be practical.

Visualization of CO electrolysis using optical coherence tomography.

Electrolysers offer an appealing technology for conversion of CO into high-value chemicals. However, there are few tools available to track the reactions that occur within electrolysers. Here we report an electrolysis optical coherence tomography platform to visualize the chemical reactions occurring in a CO electrolyser.

High-Efficiency Perovskite Solar Cells with Sputtered Metal Contacts.

Sputter deposition produces dense, uniform, adhesive, and scalable metal contacts for perovskite solar cells (PSCs). However, sputter deposition damages the other layers of the PSC. We here report that the damage caused by sputtering metal contacts can be reversed by aerial oxidation.

Electrolysis Can Be Used to Resolve Hydrogenation Pathways at Palladium Surfaces in a Membrane Reactor.

For common hydrogenation chemistries that occur at high temperatures (where H is adsorbed and activated at the same surface which the substrate must also adsorb for reaction), there is often little consensus on how the reactions (e.g., hydro(deoxy)genation) actually occur.