Transfer Hydrogenation Catalyzed by a Bifunctional Cobalt-Based Supramolecular Complex Offering Hydrogen Bonding Cavities.

A cobalt-containing supramolecular complex, Co-L, is presented, offering dual functionalities. Co-L contains both Lewis acidic-basic sites provided by the cobalt ions and hydroxyl groups, and Brønsted acid sites from the free carboxylic acid groups. This complex forms a 3D layered structure via assorted intra-layer and inter-layer hydrogen bonds.

Corrosion Behavior of MgTiZn and MgTiZn Alloys After Ball Milling and Subsequent Spark Plasma Sintering.

Magnesium-containing multi-principal element alloys (MPEAs) are promising for lightweight applications due to their low density, high specific strength, and biocompatibility. This study examines two Mg-Ti-Zn alloy compositions, equal molar MgTiZn (TZ) and MgTiZn (4TZ), synthesized via ball milling followed by spark plasma sintering, focusing on their microstructures and corrosion behaviors. X-ray diffraction and transmission electron microscopy revealed the formation of intermetallic phases, including TiZn and MgZn in TZ, while 4TZ exhibited a predominantly Mg-rich phase.

The burden of cardiovascular events according to cardiovascular risk profile in adults from high-income, middle-income, and low-income countries (PURE): a cohort study.

Background: Current strategies to prevent adverse cardiovascular outcomes focus primary prevention in high-risk groups and secondary prevention in people with known cardiovascular disease. We aimed to determine the proportion of events occurring in lower-risk groups globally.

Methods: We included people aged 40 years to younger than 75 years who were enrolled in the Prospective Urban Rural Epidemiology (PURE) study, which is an ongoing, international, prospective, population-based cohort study that started recruiting adults from households selected to be broadly representative of the sociodemographic composition of their communities.

Phenotypic data related to seedling traits of hexaploid spring wheat panel evaluated under salinity stress.

Salt stress is a major abiotic stress affecting wheat at various developmental stages and significantly reduces grain yield. Developing salt resilient wheat cultivars alleviate the negative impacts of salt stress and helps in maintaining sustainable grain yield under salt stress. A study was undertaken to assess the response of various seedling traits in a genetically, phenotypically, and geographically diverse panel of 228 hexaploid spring wheat accessions using greenhouse lysimeter system with two irrigation treatments: control (electrical conductivity of irrigation water as deci-Siemens per meter.

Integrated use of biochar, Cassia fistula, and Trichoderma for sustainable management of Sclerotium rolfsii in chickpea.

Background: is a devastating soil borne pathogen causing collar rot in chickpea, leading to significant crop yield losses. Sustainable diseases management strategies are required to reduce dependence on chemical fungicides and mitigate environmental hazards risks. Biochar, a carbon-rich soil amendment, improves soil health and enhances soil microbial activity, aiding in soil borne disease suppression.

Understanding the genetic basis of heat stress tolerance in wheat (Triticum aestivum L.) through genome-wide association studies.

Heat stress can reduce the production potential of wheat (Triticum aestivum L.) by affecting the various developmental stages of wheat including the seedling stage. Understanding the genetic basis of heat stress tolerance can help in breeding resilient wheat cultivars with improved productivity.

Visible Light Catalyzed Oxidative Reactions Using Silver-Based Metal-Organic Frameworks Based on Metalloligands.

Photocatalysis plays a crucial role in modern organic synthesis by enabling efficient transformations under mild conditions and reducing the need for harmful reagents. Its ability to harness visible light for sustainable chemical processes makes it an attractive alternative to conventional methods. In this study, we have utilized two silver-based MOFs, incorporating two different Co-metalloligands, as photocatalysts for oxidation reactions and oxidative coupling processes.

Chronic statin-use before PCI in acute coronary syndromes and in-hospital outcomes: ACC-NCDR registry in India.

Objective: To compare in-hospital major cardiovascular adverse outcomes among chronic statin-user and statin-naïve acute coronary syndrome(ACS) patients following percutaneous coronary intervention(PCI).

Methods: Successive patients with ACS who underwent PCI from Sep'17 to Dec'23 were enrolled in a prospective registry. Details of risk factors, presentation, angiography, interventions, and in-hospital outcomes were recorded.

Unprecedented Hydrogen Evolution Reactions Based on the Accelerating Effect of [Co-Tb]-Supramolecular Complex-Anchored CdS Heterojunctions.

This study presents a series of /CdS binary heterojunctions, synthesized by combining (a Co-Tb-based supramolecular complex) and CdS in various weight ratios via a solvothermal process. These heterojunctions have been thoroughly characterized to elucidate their chemical, structural, and optoelectronic properties. The catalytic effectiveness of these heterojunctions was evaluated with respect to the hydrogen evolution reaction (HER), spanning photocatalytic, electrocatalytic, and photoelectrocatalytic processes.

Clonal evolution and the risk of secondary myeloid neoplasia following chimeric antigen receptor T-cell therapy.

Not available.

HLA-DR positive acute promyelocytic leukaemia (APML) with cryptic PML::RARA fusion.

We report the case of a 42-year-old female presented with cytopenia and abnormal promyelocytes on blood film. The promyelocytes were HLA-DR positive by flow cytometry. The rapid FISH for PML::RARA was negative.