Highly efficient detection of fluoride in using silole-based electrochemiluminescence analysis.

The content of fluoride has a vital impact on the performance of the traditional Chinese medicine , and hence, developing efficient fluoride detection methods is crucial. In this work, we designed and prepared a spirosilole SBS with a typical rigid structure. Calculations and experiments fully disclosed that the rigid structure could remarkably boost its ECL signal in a homogeneous organic solution.

Bright Luminescence of Free Radical TEMPO Enabled by Electrochemiluminescence Technique.

Radicals can feature theoretically 100% light utilization owing to their nonelectron spin-forbidden transition and represent the most advanced luminescent materials at present. 2,2,6,6-Tetramethyl-1-piperidinyloxy (TEMPO) acts as a typically stable radical with very broad applications. However, their luminescent properties have not been discovered to date.

Species selective concentration and determination of nano-selenium and inorganic selenium species in environmental waters by micropore membrane filtration and ICP-MS.

Accurate quantification of nano-selenium (nSe) and other ionic Se species in aquatic environments is a prerequisite for reliable estimation of their potential hazards. In this study, a micropore membrane filtration-based method followed by ICP-MS analysis was proposed for the selective concentration and determination of nSe in the water column. Polyvinylidene fluoride (PVDF) and nylon micropore filtration membranes were proven to efficiently capture nSe under optimal conditions (retention > 91.

Speciation of Selenium Nanoparticles and Other Selenium Species in Soil: Simple Extraction Followed by Membrane Separation and ICP-MS Determination.

The application of selenium nanoparticle (SeNP)-based fertilizers can cause SeNPs to enter the soil environment. Considering the possible transformation of SeNPs and the species-dependent toxicity of selenium (Se), accurate analysis of SeNPs and other Se species present in the soil would help rationally assess the potential hazards of SeNPs to soil organisms. Herein, a novel method for speciation of SeNPs and other Se species in soil was established.

Opportunities for the use of selenium nanoparticles in agriculture.

Due to the growing number of the world's population, there is an urgent need for high-quality food to meet global food security. Traditional fertilizers and pesticides face the problems of low utilization efficiency and possible hazards to non-target organisms. Selenium (Se) is an essential trace element for animals and humans.