Prospects of sustainable polymers.

Synthetic polymers have shown a great impact on every aspect of our life and attained an exponential rise in their production and utilization in the past decades due to their durability, flexibility, moldability, and inexpensive nature. However, the use of natural polymers or development of safe and environment-friendly synthetic bio-based polymers is continuously undergoing for a sustainable future owing to the exhaustion of petroleum-based resources or fossil-based materials, disposal and economical concerns, including government guidelines. In this regard, the development of new sustainable polymers or materials will step up and build a genuinely circular economy by decreasing manufacture or utilization of fossil-based materials as limited reserves.

A Review on Biomedical Application of Polysaccharide-Based Hydrogels with a Focus on Drug Delivery Systems.

Over the last years of research on drug delivery systems (DDSs), natural polymer-based hydrogels have shown many scientific advances due to their intrinsic properties and a wide variety of potential applications. While drug efficacy and cytotoxicity play a key role, adopting a proper DDS is crucial to preserve the drug along the route of administration and possess desired therapeutic effect at the targeted site. Thus, drug delivery technology can be used to overcome the difficulties of maintaining drugs at a physiologically related serum concentration for prolonged periods.

Electromagnetic field controlled domain wall displacement for induced strain tailoring in BaTiO-epoxy nanocomposite.

Failure in an epoxy polymer composite material is prone to initiate by the coalescence of microcracks in its polymer matrix. As such, matrix toughening via addition of a second phase as rigid or/and rubber nano/micro-particles is one of the most popular approaches to improve the fracture toughness across multiple scales in a polymer composite, which dissipates fracture energy via deformation mechanisms and microcracks arrest. Few studies have focused on tailorable and variable toughening, so-called 'active toughening', mainly suggesting thermally induced strains which offer slow and irreversible toughening due to polymer's poor thermal conductivity.

Novel synthesis methods and applications of MXene-based nanomaterials (MBNs) for hazardous pollutants degradation: Future perspectives.

MXenes are a quickly growing and extended group of two-dimensional (2D) substances that have earned unbelievable analysis credits for various application areas within different manufacturing areas. Due to novel essential architectural and physicochemical properties shows good properties, such as elevated exterior area, living adaptability, strong electrochemistry, and great hydrophilicity. Given the fast progress within the structure and synthesis of MBNs for water treatment, quick updates on this research field are required to remove toxic substances, such as production approaches and characterization methods for the advantages and constraints of MXenes for pollutant degradation.

Tailoring of Thermo-Mechanical Properties of Hybrid Composite-Metal Bonded Joints.

Metallic substrates and polymer adhesive in composite-metal joints have a relatively large coefficient of thermal expansion (CTE) mismatch, which is a barrier in the growing market of electric vehicles and their battery structures. It is reported that adding carbon nanotubes (CNTs) to the adhesive reduces the CTE of the CNT-enhanced polymer adhesive multi-material system, and therefore when used in adhesively bonded joints it would, theoretically, result in low CTE mismatch in the joint system. The current article presents the influence of two specific mass ratios of CNTs on the CTE of the enhanced polymer.

Carbon nanotube embedded adhesives for real-time monitoring of adhesion failure in high performance adhesively bonded joints.

Carbon nanotubes (CNTs) embedded polymers are of increasing interest to scientific and industrial communities for multi-functional applications. In this article, CNTs have been introduced to high-strength epoxy adhesive for enabling in-situ strain sensing in adhesively bonded aluminium-to-aluminium single-lap joints to accurately indicate the onset and propagation of adhesion failure to the evolution of piezo-resistivity in varying mechanical loads. The CNT modified adhesive in bonded joints and the CNT modified adhesive alone have been tested under monothonic and cyclic tensile loads up to ultimate failure.

Microwave-Assisted Rapid Synthesis of Reduced Graphene Oxide-Based Gum Tragacanth Hydrogel Nanocomposite for Heavy Metal Ions Adsorption.

Reduced graphene oxide (RGO) was synthesized in this research via Tour's method for the use of filler in the hydrogel matrix. The copolymerization of ,-dimethylacrylamide (DMA) onto the gum tragacanth (GT) was carried out to develop gum tragacanth-cl-,-dimethylacrylamide (GT-cl-poly(DMA)) hydrogel using ,'-methylenebisacrylamide (NMBA) and potassium persulfate (KPS) as cross-linker and initiator correspondingly. The various GT-cl-poly(DMA) hydrogel synthesis parameters were optimized to achieve maximum swelling of GT-cl-poly(DMA) hydrogel.

Comparison of Cooled and Uncooled IR Sensors by Means of Signal-to-Noise Ratio for NDT Diagnostics of Aerospace Grade Composites.

This work aims to address the effectiveness and challenges of non-destructive testing (NDT) by active infrared thermography (IRT) for the inspection of aerospace-grade composite samples and seeks to compare uncooled and cooled thermal cameras using the signal-to-noise ratio (SNR) as a performance parameter. It focuses on locating impact damages and optimising the results using several signal processing techniques. The work successfully compares both types of cameras using seven different SNR definitions, to understand if a lower-resolution uncooled IR camera can achieve an acceptable NDT standard.

Electrospun Piezoelectric Polymer Nanofiber Layers for Enabling in Situ Measurement in High-Performance Composite Laminates.

This article highlights the effects from composite manufacturing parameters on fiber-reinforced composite laminates modified with layers of piezoelectric thermoplastic nanofibers and a conductive electrode layer. Such modifications have been used for enabling in situ deformation measurement in high-performance aerospace and renewable energy composites. Procedures for manufacturing high-performance composites are well-known and standardized.

Effect of Morphological Changes due to Increasing Carbon Nanoparticles Content on the Quasi-Static Mechanical Response of Epoxy Resin.

Mechanical failure in epoxy polymer and composites leads them to commonly be referred to as inherently brittle due to the presence of polymerization-induced microcrack and microvoids, which are barriers to high-performance applications, e.g., in aerospace structures.