Excitons in monolayer transition metal dichalcogenides (TMDs) possess the valley degree of freedom (DOF), which is regarded as a pseudospin (in addition to charge and spin DOF) and can be addressed optically by using polarized light. Incorporating monolayer TMDs into an optical microcavity in the strong coupling regime further enables the formation of valley polaritons that are half-light and half-matter quasiparticles with addressable spin and momentum through the spin-orbit interactions of light, in analogy with the spin-Hall effect in electronic systems. By placing monolayer TMDs on a plasmonic metasurface to enable strong coupling between excitons and surface plasmon polaritons (SPPs), we report here the observation of valley resolved polaritons in momentum space and a large separation in real space.
View Article and Find Full Text PDFA moiré superlattice formed in twisted van der Waals bilayers has emerged as a new tuning knob for creating new electronic states in two-dimensional materials. Excitonic properties can also be altered drastically due to the presence of moiré potential. However, quantifying the moiré potential for excitons is nontrivial.
View Article and Find Full Text PDFCedrol is a natural sesquiterpene alcohol found in , which has been proven to have a broad spectrum of biological activities, such as antimicrobial, anti-inflammatory, analgesic, anxiolytic, and anti-cancer effects. However, the underlying anticancer mechanisms and inhibitory effects of cedrol on colorectal cancer (CRC) have not been elucidated. In the present study, we investigated the anti-CRC potential of cedrol using and models.
View Article and Find Full Text PDFTwo-dimensional (2D) semiconducting monolayers such as transition metal dichalcogenides (TMDs) are promising channel materials to extend Moore's Law in advanced electronics. Synthetic TMD layers from chemical vapor deposition (CVD) are scalable for fabrication but notorious for their high defect densities. Therefore, innovative endeavors on growth reaction to enhance their quality are urgently needed.
View Article and Find Full Text PDFJuniperus communis (JCo) is a well-known traditional Chinese medicinal plant that has been used to treat wounds, fever, swelling, and rheumatism. However, the mechanism underlying the anticancer effect of JCo extract on colorectal cancer (CRC) has not yet been elucidated. This study investigated the anticancer effects of JCo extract in vitro and in vivo as well as the precise molecular mechanisms.
View Article and Find Full Text PDFHepatocellular carcinoma (HCC) is the most common type of primary liver cancer and accounts for the fourth leading cause of all cancer deaths. Scientific evidence has found that plant extracts seem to be a reliable choice due to their multitarget effects against HCC. Juniperus communis has been used for centuries in traditional medicine and its anticancer properties have been reported.
View Article and Find Full Text PDFTwo-dimensional transition metal dichalcogenide nanoribbons are touted as the future extreme device downscaling for advanced logic and memory devices but remain a formidable synthetic challenge. Here, we demonstrate a ledge-directed epitaxy (LDE) of dense arrays of continuous, self-aligned, monolayer and single-crystalline MoS nanoribbons on β-gallium (III) oxide (β-GaO) (100) substrates. LDE MoS nanoribbons have spatial uniformity over a long range and transport characteristics on par with those seen in exfoliated benchmarks.
View Article and Find Full Text PDF2D van der Waals ferroelectrics have emerged as an attractive building block with immense potential to provide multifunctionality in nanoelectronics. Although several accomplishments have been reported in ferroelectric switching for out-of-plane ferroelectrics down to the monolayer, a purely in-plane ferroelectric has not been experimentally validated at the monolayer thickness. Herein, an in-plane ferroelectricity is demonstrated for micrometer-size monolayer SnS at room temperature.
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2020
To explore the potential of field-effect transistors (FETs) based on monolayers (MLs) of the two-dimensional semiconducting channel (SC) for spintronics, the two most important issues are to ensure the formation of variable low-resistive tunnel ferromagnetic contacts (FCs) and to preserve intrinsic properties of the SC during fabrication. Large Schottky barriers lead to the formation of high resistive contacts, and methods adopted to control the barriers often alter the intrinsic properties of the SC. This work aims at addressing both issues in fully encapsulated ML WSe FETs using bilayer hexagonal boron nitride (h-BN) as a tunnel barrier at the FC/SC interface.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2019
Single crystalline Ag films on dielectric substrates have received tremendous attention recently due to their technological potentials as low loss plasmonic materials. Two different growth approaches have been used to produce single crystalline Ag films previously. One approach is based on repetitive cycles of a two-step process (low temperature deposition followed by RT annealing) using molecular beam epitaxy (MBE), which is extremely time-consuming due to the need for repeat growth cycles.
View Article and Find Full Text PDFTwo-dimensional (2D) semiconductors, particularly the direct-gap monolayer transition metal dichalcogenides (TMDs), are currently being developed for various atomically thin optoelectronic devices. However, practical applications are hindered by their low quantum efficiencies in light emissions and absorptions. While photonic cavities and metallic plasmonic structures can significantly enhance the light-matter interactions in TMDs, the narrow spectral resonance and the local hot spots considerably limit the applications when broadband and large area are required.
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