Quantum Chemical Modeling of Superbase-Mediated Self-Organization of Pyrroles from Acetylenes and Nitriles.

In this work, the superbase-mediated self-organization of tetrasubstituted pyrroles from three molecules of acetylenes and one molecule of nitriles was theoretically investigated. On the example of interaction of phenylacetylene with benzonitrile in the KOBu/DMSO medium, three possible pathways of the assembly of 2-benzyl-3,5-diphenyl-4-phenylethynyl-1-pyrrole have been studied using a combined B2PLYP-D3/6-311+G**//B3LYP-D3/6-31+G* quantum chemical approach. The calculated activation barriers correspond to mild reaction conditions (room temperature for 15 min).

Analysis of the work of the inpatient military hospital during the Russian-Ukrainian war.

Objective: Aim: The aim of this work is to analyze the provision of medical care to military personnel on the example of the activities of the Poltava Military Hospital (Poltava, Ukraine) for the period 2021-2023.

Patients And Methods: Materials and Methods: The design of our study was descriptive. During the research, the reporting and accounting documentation of the Poltava Military Hospital for the relevant years was used.

Probing the Quantum Capacitance of Rydberg Transitions of Surface Electrons on Liquid Helium via Microwave Frequency Modulation.

We present a method for probing the quantum capacitance associated with the Rydberg transition of surface electrons on liquid helium using radio-frequency (rf) reflectometry. Resonant microwave excitation of the Rydberg transition induces a redistribution of image charges on capacitively coupled electrodes, giving rise to a quantum capacitance originating from adiabatic state transitions and the finite curvature of the energy bands. By applying frequency-modulated resonant microwaves to drive the Rydberg transition, we systematically measured a capacitance sensitivity of 0.

Strong Magnon-Phonon Coupling in the Kagome Antiferromagnets.

Magnon-phonon hybridization in ordered materials is a crucial phenomenon with significant implications for spintronics, magnonics, and quantum materials research. We present direct experimental evidence and theoretical insights into magnon-phonon coupling in Mn_{3}Ge, a kagome antiferromagnet with noncollinear spin order. Using inelastic x-ray scattering and ab initio modeling, we uncover strong hybridization between planar spin fluctuations and transverse optical phonons, resulting in a large hybridization gap of ∼2  meV.

Observation of Three Resonant Structures in the Cross Section of e^{+}e^{-}→π^{+}π^{-}h_{c}.

Using e^{+}e^{-} collision data collected with the BESIII detector operating at the Beijing electron positron collider, the cross section of e^{+}e^{-}→π^{+}π^{-}h_{c} is measured at 59 points with center-of-mass energy sqrt[s] ranging from 4.009 to 4.950 GeV with a total integrated luminosity of 22.

One- versus two-stent stenting strategies in coronary bifurcation lesions.

Objectives: Additional studies are needed on the follow-up outcomes of 1- vs 2-stent techniques in bifurcation percutaneous coronary interventions (PCI).

Methods: The authors examined the angiographic and procedural characteristics, and outcomes of 1306 bifurcation PCIs (1139 patients) performed at 6 centers between 2014 and 2024 from the PROGRESS-BIFURCATION registry.

Results: Upfront 1-stent PCI (96.

Bridging feeling and motion: Insula-premotor dynamics in the processing of action vitality forms.

Typically, people perform actions in a valenced-positive or negative-way, depending on their attitudes or desires. These forms of action are named vitality forms (VFs). While it is well established that action goals are mediated by a parieto-frontal network, less is known about the processing of VFs.

[Analysis of publications on the history of forensic medicine in the «Forensic medical expertise» journal (1958-2023)].

The article presents the study results of publications on the history of forensic medicine in the Forensic Medical Expertise journal for the 1958-2023. The data on the number of publications for the entire specified period are presented, the author's composition and their publication activities have been analyzed. The analysis of publications with classification by the same type of directionality was carried out, the most common thematic units are highlighted.

[Petr Petrovich Einbrodt - a pioneer of forensic ballistics in Russia (to the 200th anniversary of the first national work on gunshot wound)].

Unlabelled: In 2024, the 200th anniversary of the first domestic work devoted to the study of gunshot injury was celebrated.

Objective: To present little-known information from the biography of its author, Professor P.P.

[Forensic medical assessment of fractures' morphological criteria for determination of the mechanisms of tibial shaft destruction in case of fall from height].

The study objective was to investigate the tibia fractures morphology depending on the position of victim at the time of injury when falling from height. The article presents the results of mathematical statistics which was carried out to justify scientifically the expert approach to reconstruction of accident circumstances in a fall from height with various landing options. The study results can be used to determine the position of the victim's body at the moment of landing, as well as to specify the height of fall.

[Modern view on the mechanism of traffic injury in collision of moving vehicle and pedestrian].

The article considers the main phases of traffic injury (TI) described by A.A. Solokhin in 1968 and their modern application in forensic medical and automotive examination.

[Mathematical programming in assessment of the postmortem interval under conditions of linearly varying external temperature].

Objective: To develop and implement a method for determining the postmortem interval and the marginal errors of its estimates under conditions of linearly varying external temperature in the format of an online application.

Material And Methods: A computer-assissted numerical search for the absolute minimum point of the objective function obtained from a system of nonlinear equations reflecting the results of double rectal or cranioencephalic thermometry of a corpse under conditions of linearly varying external temperature was carried out. The search algorithm was generalized to possible marginal errors in measuring the initial indicators of temperature and time.

[Organ and species identification of liver microparticles using forensic cytology and quantitative enzyme-linked immunosorbent assay methods].

Objective: To establish organ affiliation of liver microparticles using forensic cytological method based on hepatocytes' morphological characteristics and to determine their species belonging according to the human IgG using a quantitative enzyme-linked immunosorbent assay (ELISA).

Material And Methods: Previously dried microparticles (from 0.2×0.

[On the possibility of establishing postmortem interval of human by examining the electrical conductivity of the knee joints' synovial fluid].

Objective: To study the electrical conductivity of the knee joints' synovial fluid of human's corpse for assessment of the possibility of its application as criterion of forensic medical diagnosis of postmortem interval.

Material And Methods: The work was carried out on practical forensic medical material on the basis of the Bureau of Forensic Medical Expertise in the Republic of Bashkortostan. During the study, 103 corpses of both sexes, different ages who died from various causes were investigated.

[Mechanism and features of blood vessel damage around the gunshot wound canal].

Unlabelled: Forming wound canal is one of the main signs of gunshot wound. Its features are related to the following differential diagnostic signs: presence of gunshot wound, its intravitality, prescription, direction of projectile (bullet) movement, power of used weapon, etc.

Objective: To study the mechanisms of wound canal formation in gunshot injury, the pattern of damage to the biological tissues of its walls (mainly, blood vessels), the features of hemorrhages forming around it.

[To determination of the causal relationship between the actions of medical professionals and the occurrence of adverse outcome in expertises on medical malpractice cases].

Two expert reports of medical malpractice cases, in one of which there was a conclusion about the presence of a direct causal relationship with the natural course of the disease, and the other - with the incorrect actions of the doctor, were analyzed. Methodological approaches to solving such issues are discussed. It is recommended to use the logical method of hypothetical elimination of incorrect actions of medical professionals in order to avoid errors.

[Forensic medical expertise in the cases of sexual crimes: dynamics of indicators and regional features].

Unlabelled: Crimes against the sexual integrity of the individual represent one of the most serious forms of violence.

Objective: To perform a retrospective epidemiological analysis with the systematization of analytical data on the performed forensic medical examinations (FMEs) of survivors of sexual abuse in order to increase the effectiveness of the system of preventive measures against such crimes.

Material And Methods: The data from the industry statistical report №42 were analyzed.

Genetic variants in HSP40 co-chaperones modulate ischemic heart disease risk.

Background: The chaperoning system, which is responsible for protein homeostasis, plays a significant role in cardiovascular diseases. Among molecular chaperones or heat shock proteins (HSPs), the HSP40 family, the main co-chaperone of HSP70, remains largely underexplored, especially in ischemic heart disease (IHD) risk.

Materials And Results: We genotyped 834 IHD patients and 1,328 healthy controls for three SNPs (rs2034598 and rs7189628 DNAJA2 and rs4926222 DNAJB1) using probe-based real-time PCR.

Intermolecular Lithium η-Alkene and κ-Alkane Complexes: Synthesis, Bonding, and Facile Interconversion.

In this work, an approach enabling the synthesis of η-alkene lithium complexes (Carb)Li(η-L) (L = 1-octene, cyclohexene) is elaborated. For 1,5-hexadiene, the same approach results in a binuclear μ-η:η-diene complex. The QTAIM parameters reveal the electrostatic nature of the Li-alkene interaction.

Antifungal Prescribing in European Pediatric Intensive Care Units: Results of a multinational 3-month weekly point-prevalence survey.

Background: Critically ill pediatric patients admitted to the PICU are highly vulnerable to infections, including invasive fungal diseases and antifungal agents are frequently prescribed. Little is known about antifungal usage in PICUs across Europe.

Methods: A multinational 3-month weekly point-prevalence study for measuring antifungal drug use was organized.

Vulvar and vaginal cancer during pregnancy: A pooled analysis of 15 cases from the International Network on Cancer, Infertility and Pregnancy and review of the literature.

Introduction: Vulvovaginal cancer in pregnancy is rare. Limited data complicate decision-making and patient counseling. Our review, coupled with new case data, fills a current gap in the literature and provides practical insights.

A tetraphosphino-bis(-triazine) from cyanuric chloride and PhPH: new unexpected tandem C-C/C-P coupling reaction.

Serendipitous synthesis of 4,4',6,6'-tetrakis(diphenylphosphino)-2,2'-bi(-triazine) (Tr2P4) - a novel promising polyphosphine ligand - from cyanuric chloride and diphenylphosphine is reported. This unusual reaction represents the first example of tandem C-C/C-P coupling between (het)aryl halides and P-H species, yielding a structurally unique bi(hetaryl)-tetraphosphine. Theoretical study indicates that the 2,2'-bi(-triazine) core arises from hydrolysis of an intermediate [PhP(TrCl)] salt, formed through quaternization of monophosphine Tr(PPh)Cl with cyanuric chloride.

Predictors of the Development of Newly Diagnosed Chronic Heart Failure in Patients with Shortness of Breath in Long-Term Post-COVID Syndrome.

Aim     To determine the prevalence and predictors for the development of newly diagnosed chronic heart failure (CHF) in patients with shortness of breath in long-term post-COVID syndrome.Material and methods            This screening cross-sectional clinical study was performed from April 2020 through April 2024, in two stages in an outpatient setting. At the first stage, 878 patients with shortness of breath were screened three or more months after COVID-19, and the presence of at least three diagnostic criteria for CHF, that were not in their history, was verified.

Analysis of 17 Factors Potentially Related to Hypertension Control in the Siberian Urban Sample.

Aim        To identify non-pharmacological factors associated with ineffective blood pressure (BP) control among individuals with arterial hypertension (AH) in a Siberian urban population sample.Material and methods          A considerable proportion of individuals with AH does not achieve BP goals. BP control is influenced by a number of non-drug determinants, including non-modifiable and multiple modifiable factors.