The occurrence, distribution and ecological risk assessment of bisphenol A and phthalate acid esters in the semi closed ship-port sediments of south coastline Istanbul, Turkey.

Bisphenol analogues and phthalate acid esters are well-known endocrine disruptors. Information on detailed distribution and partitioning of Bisphenol A (BPA) and Phthalate acid esters (PAEs) in port sediments is essential for a better understanding of their residence time in sediment, influence of anthropogenic activities in port, and port sustainability, especially in terms of environmental impact. Herein, this study determined the concentrations of BPA and PAEs in sediments that are collected from 38 stations from Istanbul ship-ports and scrutinized distribution, possible source identification and potential environmental risk assessment.

Multifunctionalized Conductive Polymers for Self-Healing Silicon Anodes in Li-Ion Batteries.

Silicon is a very promising material for lithium-ion batteries (LIBs) due to its high theoretical capacity (3579 mAh/g). However, the volumetric expansion (300%) of silicon during lithiation led to pulverization of the electrode and rapid capacity fading. Self-healing (SH) materials are thought of as a solution for the degradation of active materials, enabling higher capacity retention.

The development of a novel, green, efficient, and eco-friendly GC-MS/MS analytical method for the reliable and rapid determination of dl-PCBs, and PCDD/Fs using hydrogen as a carrier gas and a modified ion source.

The polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (dl-PCBs) are worldwide contaminants, and they tend to accumulate in wide variety of matrices. Therefore, due to the highest accumulation rate and recalcitrancy, their precise quantification makes significant concern about their toxicological effects on both humans and organisms. The objective of the study is that using hydrogen carrier gas instead of helium in gas chromatography with triple quadrupole (GC-MS/MS) systems could contribute to improvements on the analysis of dl-PCBs and PCDD/Fs in environmental matrices.

Ecotoxicological risk assessments and components of persistent organic pollutants and metals in the historical settlement area (Iznik (Nicea) lake) large water resource sediments.

The main objectives of this study are to measure permanent organic and inorganic pollutants in detail in an area that hosts historical structures underneath and feeds the huge ecosystem with water, to reveal risk values. Total PAH concentrations in the samples ranged from 43.41 to 202.

Evaluation of hexabromocyclododecane (HBCD), polybrominated dibenzo-p-dioxins/furans (PBDD/Fs) and polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) outflows during the destruction of HBCD wastes in a hazardous waste incinerator.

This paper presents an evaluation of hexabromocyclododecane (HBCD), polybrominated dibenzo-p-dioxins/furans (PBDD/Fs) and polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) outflows during the destruction of HBCD waste stockpiles in IZAYDAS Hazardous Waste Incinerator (HWI) in Kocaeli, Türkiye. HBCD wastes containing 100 % pure HBCD were in 25 kg packages with 63 % Br content were co-incinerated in a 3-day test burn with average feed rate of 26 kg/h. HBCD, PBDD/Fs and PCDD/Fs were measured in the outlet streams to quantify the amount of unintended POPs releases associated with the processing of HBCD waste and to observe the POP removal performance of air pollution control equipment (APCE) of the incinerator.

Investigation of organic micropollutant pollution in İzmit Bay: a comparative study of passive sampling and instantaneous sampling techniques.

In this study, we used a comprehensive array of sampling techniques to examine the pollution caused by organic micropollutants in İzmit Bay for the first time. Our methodology contains spot seawater sampling, semi-permeable membrane devices (SPMDs) passive samplers for time-weighted average (TWA), and sediment sampling for long-term pollution detection in İzmit Bay, together. Additionally, the analysis results obtained with these three sampling methods were compared in this study.

Assessing cytotoxic activities, theoretical and molecular docking calculations of phthalocyanines bearing cinnamyloxy-groups.

Cancer has been recognized as one of the deadliest diseases in the world in recent years. By chemically tailoring specific properties, anticancer agents can be prepared very effectively for the treatment of various cancer types. In this manner, as anticancer agents, a series of soluble metal-free and metallophthalocyanines carrying cinnamyloxy-groups at peripheral β-positions have been prepared.

A comprehensive assessment, source input determination and distribution of persistent organic pollutants (POPs) along with heavy metals (HMs) in reservoir lake sediments from Çanakkale province, Türkiye.

This study presents the distribution of persistent organic pollutants (POPs), polycyclic aromatic hydrocarbons (PAHs) and heavy metals (HMs) in the sediments from four dams and two ponds in the Çanakkale city, Türkiye. The total concentration varied from 41.47 to 145.

Self-Healing Systems in Silicon Anodes for Li-Ion Batteries.

Self-healing is the capability of materials to repair themselves after the damage has occurred, usually through the interaction between molecules or chains. Physical and chemical processes are applied for the preparation of self-healing systems. There are different approaches for these systems, such as heterogeneous systems, shape memory effects, hydrogen bonding or covalent-bond interaction, diffusion, and flow dynamics.

The first observation of antifouling organotin compounds and booster biocides in sediments from Samsun Port area, Black Sea, Turkey.

The distribution of antifouling organotin compounds (OTCs) and booster biocides in surface sediments of Samsun Port (Black Sea, Turkey) in September 2014 was investigated by gas chromatography-tandem mass spectrometry (GC-MS/MS) method. The total organotin concentrations ranged from <1.0 to 669.

Effective removal of Cs ions from radioactive wastewater by Melamine-Styrene based Polymer (MSP).

Cesium (Cs) is a major product of uranium fission, which is one of the most existed radionuclides in radioactive wastes. Removal of Cs-137 has a critical role in the decontamination of liquid radioactive waste due to its half-life of 30.17 years.

Assessment of distribution of heavy metals and activity level of Pb in biota from the northern coast of the Marmara Sea and Western Black Sea.

In this study, heavy metals (Cd, Co, Cu, Ni, Pb, Zn, V) and Pb analyses have been performed in the marine biota (scaldfish, sea lettuce, crab). Samples were collected from 5 different parts of the Marmara Sea and Western Black Sea in January 2020. The results indicated that the highest Cu and Zn content was found in algae samples, but it was observed that heavy metal concentrations such as Co, Cu, Cd and V were generally low and under permissible limit.

Mercury and Po-210 in mollusc species in the island of Gökçeada in the north-eastern Aegean Sea: Bioaccumulation and risk assessment for human consumers.

Among the radioactive pollutants Po is the most substantial one in terms of seafood safety due to its efficient accumulation in marine animals and high irradiation of its alpha emission. Mercury is a highly toxic metal for both marine organisms and human beings. Biomagnification of MeHg (methylmercury) through marine food chains has made Hg concern of ecotoxicology and seafood safety.

A radioactively durable melamine-styrene based polymer: Highly efficient removal of Sr.

Removal of strontium has a vital importance for radioactive waste management due to its long half-life. In this context, melamine-styrene based polymer (MSBP) was synthesized and characterized by different spectrophotometric methods. Sr ions were removed from the solution using MSBP sorbent.

Monitoring the antioxidant activities by extracting the polyphenolic contents of algae collected from the Bosphorus.

The identification and quantification of ascorbic acid, phenolic acids and flavonoids were carried out simultaneously with a rapid method of reverse-phase high-performance liquid chromatography (RP-HPLC). Total flavonoid contents were being determined by UV-Vis spectrophotometry, and total phenolic contents were determined by UV-Vis spectrophotometry using the Folin-Ciocalteu Reagent (FCR) method. In all of the individual contents and total phenolic content analysis, the best results were obtained with the methanol-water solvent system.

Ecological Risk Assessment of HCH and DDT Residues in a Sediment Core from the Küçükçekmece Lagoon, Turkey.

The residues of organochlorine pesticides (HCHs and DDTs) in a dated (Cs and Pb) sediment core from the Küçükçekmece Lagoon, an urban lake at the southern entrance of the future Canal Istanbul Project, an artificial watercourse, were analyzed with the gas chromatograph equipped with electron capture detector (GC Ni-ECD). Concentrations of ∑HCH and ∑DDT along the core varied between 0.4 and 469.

Geochronology and sources of heavy metal pollution in sediments of Istanbul Strait (Bosporus) outlet area, SW Black Sea, Turkey.

Geochemical and sedimentological analyses and radionuclide (Pb and Cs) dating of three cores from the Bosporus outlet area of the Black Sea, north of Istanbul, were conducted to assess the sources and history of heavy metal pollution. The sedimentary succession in the shelf core KD12-01 consists mainly of clay (49-80%) and silt (15-41%). Radionuclide dating of the core indicates that it consists of old sediments that are uncontaminated with heavy metals.

Sources of metal pollution in the urban atmosphere (A case study: Tuzla, Istabul).

In this study, İstanbul-Tuzla Region atmosphere was selected as the working area for atmospheric pollution. Although the study area seems too local, this region contains shipyards and shipyard-related side product industries. It is also surrounded by aluminum (ASSAN) and copper (SARKUYSAN) facilities and tannery organized industrial district.

Seasonal variations of epipelic algal community in relation to environmental factors in the Istanbul Strait (the Bosphorus), Turkey.

This study was implemented to investigate the species composition, abundance, seasonal variations and diversity of epipelic algae, to determine environmental variables affecting them and to reveal the accumulation of total organic carbon in the sediment in the coastal zone of the Istanbul Strait, Turkey. Epipelic algal community consisted of 44 taxa with a low diversity. The sediment structure which is highly unstable due to the high hydrodynamism of the zone played a dominant role as the main factor in the epipelic algal flora along the coasts of Istanbul Strait.

Toxic metal (Pb, Cd and Hg) levels in the nearshore surface sediments from the European and Anotolian Shores of Bosphorus, Turkey.

In this study, some toxic metal such as Pb, Cd and Hg analyzes have been done in the nearshore surface sediments. Sediment samples have been collected from five parts from the European and Anotolian Shores of the Bosphorus during 2003-2004. Total Pb, Cd and Hg contents vary between <0.

Organochlorine residue and toxic metal (Pb, Cd and Cr) levels in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey.

In this study, organochlorine and toxic metal (Pb, Cd and Cr) analyses have been done in the surface sediments. Sediment samples have been collected from 7 parts of the Marmara Sea and the coast of Istanbul during 2009. Total Pb, Cd and Cr contents vary between 32 μg g(-1) and 122 μg g(-1); 0.

Metal (Al, Fe, Mn and Cu) distributions and origins of polycyclic aromatic hydrocarbons (PAHs) in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey.

In this study, total metal (Al, Fe, Mn and Cu) and PAHs analyses have been done in the surface sediments. Sediment samples have been collected from seven parts of the Marmara Sea and the coast of Istanbul during 2009. Total Al, Fe, Mn and Cu contents vary between 1.

Petroleum hydrocarbon contamination of the Southern Black Sea Shelf, Turkey.

Introduction: In this study, total petroleum hydrocarbon (TPH) contents and some aliphatic and aromatic hydrocarbon concentrations were analysed in coastal sediments of hot points collected from along the Southern Black Sea Shelf.

Materials And Methods: Surface sediment (0-2 cm) samples were collected from the locations using a Van Veen type grab sampler in September 2008 during a cruise on the Pollution Monitoring R/V ARAR. All sampling procedures were carried out according to internationally recognized guide-lines (UNEP 1991).

Toxic metal (Pb, Cd, As and Hg) and organochlorine residue levels in hake (Merluccius merluccius) from the Marmara Sea, Turkey.

Toxic metals (Pb, Cd, As and Hg) and organochlorine residue levels were measured in hake (Merluccius merluccius) from the Marmara Sea. Biota samples were collected by a trawling cruise of the R/V ARAR in August and December 2009. The concentrations of toxic metals varied between Pb, 3.