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This study addresses a critical limitation in direct bonded copper (DBC) materials used in power electronics by introducing a copper-zirconium (Cu/Zr) alloy interposing layer at the copper-ceramic interface. This novel design aims to mitigate mechanical stress induced by mismatched material properties, such as the coefficient of thermal expansion (CTE) and elastic modulus, during thermal cycling. The key findings of this study are (1) thermal fatigue improvement: Test samples with the Cu/Zr interface layer (Cu-Cu/Zr-AlN) three times enhanced thermal fatigue resistance, surviving 30 thermal cycles from -55 to 300 °C before delamination, while standard DBC substrates without the Cu/Zr layer failed after just 10 cycles, indicating a performance improvement with the Cu/Zr alloy, (2) durability projections: Based on the Coffin-Manson model, if the upper temperature is capped at 150 °C, the Cu-Cu/Zr-AlN substrates are projected to survive approximately 1372 cycles, underscoring their potential for long-term reliability, and (3) stress mitigation: The Cu/Zr alloy layer bridges the CTE disparity between copper and ceramic, reducing mechanical stress and improving structural integrity across a broad temperature range (-55 to 300 °C). This study reveals, incorporating the Cu/Zr interposing layer between Cu and AlN substrates significantly enhances the operational lifespan and reliability, making them well-suited for high-temperature and high-stress environments in advanced power electronics. This innovation demonstrates the feasibility of improving thermal fatigue performance while maintaining mechanical integrity, representing a substantial advancement over conventional DBC materials.
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http://dx.doi.org/10.1021/acsomega.5c06959 | DOI Listing |
ACS Omega
September 2025
Materials and Manufacturing Directorate, AFRL/RXEE, Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433, United States.
This study addresses a critical limitation in direct bonded copper (DBC) materials used in power electronics by introducing a copper-zirconium (Cu/Zr) alloy interposing layer at the copper-ceramic interface. This novel design aims to mitigate mechanical stress induced by mismatched material properties, such as the coefficient of thermal expansion (CTE) and elastic modulus, during thermal cycling. The key findings of this study are (1) thermal fatigue improvement: Test samples with the Cu/Zr interface layer (Cu-Cu/Zr-AlN) three times enhanced thermal fatigue resistance, surviving 30 thermal cycles from -55 to 300 °C before delamination, while standard DBC substrates without the Cu/Zr layer failed after just 10 cycles, indicating a performance improvement with the Cu/Zr alloy, (2) durability projections: Based on the Coffin-Manson model, if the upper temperature is capped at 150 °C, the Cu-Cu/Zr-AlN substrates are projected to survive approximately 1372 cycles, underscoring their potential for long-term reliability, and (3) stress mitigation: The Cu/Zr alloy layer bridges the CTE disparity between copper and ceramic, reducing mechanical stress and improving structural integrity across a broad temperature range (-55 to 300 °C).
View Article and Find Full Text PDFMolecules
June 2025
Materials Science Program, Oregon State University, Corvallis, OR 97331, USA.
The mechanical properties of materials are fundamentally determined by the behavior of atomic bonds under stress. Probing bond behavior during deformation, however, is highly challenging, particularly for materials with complex chemical compositions and/or atomic structures, such as metallic glasses (MGs). As a result, a significant gap exists in the current understanding of the mechanical properties of MGs in relation to the atomic bond behavior and how this relationship is influenced by metallurgical factors (e.
View Article and Find Full Text PDFMaterials (Basel)
March 2025
School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China.
This study investigates how Zr doping influences the deformation behavior of Cu-Zr/AlCu/Al composites through molecular dynamics simulations. The impact of Zr content (ranging from 0 to 0.8 wt%) and strain rate on phase evolution, dislocation dynamics, and fracture mechanisms under vertical and horizontal tensile loading was examined.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Key Laboratory for Liquid-Solid Structure Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan 250061, China.
Transition element microalloying is important for improving the properties of Al-Zn-Mg-Cu alloys. Nevertheless, along with its high costs, increasing Sc content generates a harmful phase, limiting the strength of the alloy. In this experiment, we reduced the amount of Sc added to a Zr-containing Al-Zn-Mg-Cu alloy by one order of magnitude.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Research Center of Digital Oral Science and Technology, College of Oral Medicine, Taipei Medical University, Taipei 110-301, Taiwan.
Bulk metallic glasses (i.e., BMGs) have attracted a lot of research and development interest due to their unique properties.
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