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It is known that the long-range quantum entanglement exhibited in free fermion systems is sufficient to "thermalize" a small subsystem in that the subsystem reduced density matrix computed from a typical excited eigenstate of the combined system is approximately thermal. Remarkably, fermions without any interactions are thus thought to satisfy the eigenstate thermalization hypothesis. We explore this hypothesis when the fermion subsystem is only minimally coupled to a quantum reservoir (in the form of another fermion system) through a quantum point contact (QPC). The entanglement entropy of two free fermion systems connected by one or more QPCs is examined at finite energy and in the ground state. When the combined system is in a typical excited state, it is shown that the entanglement entropy of a subsystem connected by a small number of QPCs is subextensive, scaling as the linear size of the subsystem (L_{A}). For sufficiently low energies (E) and small subsystems, it is demonstrated numerically that the entanglement entropy S_{A}∼L_{A}E, what one would expect for the thermodynamics of a one-dimensional system. In this limit, we suggest that the entropy carried by each additional QPC is quantized using the one-dimensional finite size and temperature conformal scaling: ΔS_{A}=αlog(1/E)sinh(L_{A}E). The subextensive entropy in the case of a small number of QPCs should be contrasted with the expectation for both classical, ergodic systems and quantum chaotic systems, wherein a restricted geometry might affect the equilibrium relaxation times but not the equilibrium properties themselves, such as extensive entropy and heat capacity.
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http://dx.doi.org/10.1103/q1jg-m49s | DOI Listing |
J Phys Chem A
September 2025
Dipartimento di Scienze Fisiche e Chimiche, Università degli Studi dell'Aquila, Coppito, L'Aquila 67100, Italy.
In recent years Quantum Computing prominently entered in the field of Computational Chemistry, importing and transforming computational methods and ideas originally developed within other disciplines, such as Physics, Mathematics and Computer Science into algorithms able to estimate quantum properties of atoms and molecules on present and future quantum devices. An important role in this contamination process is attributed to Quantum Information techniques, having the 2-fold role of contributing to the analysis of electron correlation and entanglements and guiding the construction of wave function variational ansatzes for the Variational Quantum Eigensolver technique. This paper introduces the tool SparQ (Sparse Quantum state analysis), designed to efficiently compute fundamental quantum information theory observables on post-Hartree-Fock wave functions sparse in their definition space.
View Article and Find Full Text PDFEntropy (Basel)
August 2025
Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi Arabia.
In this work, we investigate the quantum coherence and purity in hydrogen atoms under dissipative dynamics, with a focus on the hyperfine structure states arising from the electron-proton spin interaction. Using the Lindblad master equation, we model the time evolution of the density matrix of the system, incorporating both the unitary dynamics driven by the hyperfine Hamiltonian and the dissipative effects due to environmental interactions. Quantum coherence is quantified using the L1 norm and relative entropy measures, while purity is assessed via von Neumann entropy, for initial states, including a maximally entangled Bell state and a separable state.
View Article and Find Full Text PDFEntropy (Basel)
August 2025
Research Center for Astronomy and Applied Mathematics of the Academy of Athens, Soranou Efessiou 4, GR-11527 Athens, Greece.
We study in detail the critical points of Bohmian flow, both in the inertial frame of reference (Y-points) and in the frames centered at the moving nodal points of the guiding wavefunction (X-points), and analyze their role in the onset of chaos in a system of two entangled qubits. We find the distances between these critical points and a moving Bohmian particle at varying levels of entanglement, with particular emphasis on the times at which chaos arises. Then, we find why some trajectories are ordered, without any chaos.
View Article and Find Full Text PDFEntropy (Basel)
July 2025
Instituto de Física Teórica, UAM-CSIC, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
We present a graphical framework to represent entanglement in three-qubit states. The geometry associated with each and is analyzed, revealing distinct structural features. We explore the connection between this geometric perspective and the tangle, deriving bounds that depend on the entanglement class.
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July 2025
Literature, Theory, and Cultural Studies Program, Philosophy and Literature Program, Purdue University, West Lafayette, IN 47907, USA.
This article reconsiders the double-slit experiment by establishing a new type of relationship between it and the concept of entanglement. While the role of entanglement in the double-slit experiment has been considered, this particular relationship appears to have been missed in preceding discussions of the experiment, even by Bohr, who extensively used it to support his argument concerning quantum physics. The main reason for this relationship is the different roles of the diaphragm with slits in two setups, S1 and S2, defining the double-slit experiment as a quantum experiment.
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