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Conventional solidification theory asserts that eutectic phases solidify into only one specific morphology at a fixed undercooling when volume effects are negligible, while dendrites adopt rotationally parabolic tips. Here, experiments aboard China Space Station reveal that space fluid flow localization reshapes these dynamics: confined solute-thermal coupling near solid-liquid interfaces drives transitions among three eutectic growth patterns (worm-like, lamellar, faceted). Simultaneously, Marangoni convection at large undercoolings induces non-parabolic dendritic tip morphologies (dome-like, finger-like, needle-like). Spatially ordered separation of eutectic and dendritic zones is governed by localized spherically symmetric temperature and concentration fields arising from space fluid flow, whereas buoyancy-driven convection in terrestrial gravity environment disrupts this ordering, perturbing phase domain distributions. When solidified at a small undercooling, the weak convection during late stage preserves the near-perfect symmetry of dendrites under microgravity. These findings uncover novel dendritic and eutectic growth patterns under microgravity and may be applied to in-situ space manufacturing and controlled growth of crystals.
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http://dx.doi.org/10.1002/adma.202508092 | DOI Listing |
Beilstein J Nanotechnol
September 2025
Faculty of Chemical Engineering, Industrial University of Ho Chi Minh City, Vietnam.
Effective removal of trace heavy metal ions from aqueous bodies is a pressing problem and requires significant improvement in the area of absorbent material in terms of removal efficiency and sustainability. We propose an efficient strategy to enhance the adsorption efficiency of carbon nanotubes (CNTs) by growing dendrimers on their surface. First, CNTs were pre-functionalized with maleic acid (MA) via Diels-Alder reaction in presence of a deep eutectic solvent under ultrasonication.
View Article and Find Full Text PDFSmall
September 2025
Department of Materials Science and Engineering, Ludong University, Yantai, 264025, China.
With the continuous development of flexible sensors and flexible energy storage devices, gel materials with good flexibility, toughness, and tunable properties have attracted wide attention. Deep eutectic solvents (DES) have an obvious advantage of thermal and chemical stability over water. Therefore, eutectogels can effectively solve the problem of insufficient stability of traditional hydrogels.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
The Affiliated Dongguan Songshan Lake Central Hospital, Guangdong Provincial Key Laboratory of Research and Development of Natural Drugs, School of Pharmacy, Guangdong Medical University, Dongguan, 523808, China.
This study explores the extraction of polysaccharides from Nostoc commune Vauch. using ultrasonic-assisted three-phase partitioning with deep eutectic solvents (UA-TPP-DES). Response surface methodology was used to determine the optimized UA-TPP-DES conditions as follows: a 1: 2 M ratio of lauric acid to terpineol, 30 min of ultrasonication at 60 °C with 100 W power, 20 % moisture content, 20 % w/w (NH)SO concentration, and a 2: 1 top-to-bottom phase volume ratio.
View Article and Find Full Text PDFFood Chem
August 2025
School of Light Industry Science and Engineering, Beijing Technology and Business University, Beijing 100048, China.
Antibiotics are extensively used in food production for disease prevention and growth promotion, but their overuse results in food antibiotic residues, threatening human health. Thus, developing efficient, sensitive, and eco-friendly detection technologies is crucial. Deep eutectic solvents (DESs), with their green, low-toxic, tunable, and high-efficiency properties, show great potential in antibiotic analysis.
View Article and Find Full Text PDFAdv Mater
August 2025
Department of Mechanical and Industrial Engineering, University of Massachusetts, Amherst, MA, 01003, USA.
High-entropy alloys (HEAs) are promising candidates for advanced structural applications due to their excellent mechanical properties. Additive manufacturing (AM), with its rapid solidification conditions, enables the creation of unique nonequilibrium microstructures. To fully leverage the synergy between AM and HEAs, understanding how processing affects structure and properties is essential.
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