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Coherent coupling between optical modes plays a vital role in manipulating the light field and its interaction with matter. Here, we investigate the chirality-induced strong coupling between leaky guided modes (GMs) with orthogonal polarizations in a chiral metasurface waveguide in the near-infrared frequencies, which consists of a square lattice of Ge dimers with broken symmetry and an underlying SiN waveguide layer deposited on a silica substrate. We find that mode coupling between two orthogonal GMs can be induced by introducing chirality to the metasurface waveguide when illuminated with circularly polarized light. The coupling strength can be manipulated from the weak to strong coupling regime by simply changing the rotation angle of nanorods in the metasurface, enabling the generation of an exceptional point (EP) and large Rabi splitting (∼ 2 meV). Moreover, the polarization state of the hybrid mode can be continuously modified from linear to circular polarization via strong coupling. More intriguingly, we reveal that mode coupling is associated with the hybridization of circular dichroism (CD) of leaky GMs in the chiral coupled system, rendering a dual-band high CD response with a linewidth of 0.18 nm. Our findings indicate the possibility of manipulating the coupling of high-Q guided modes with chiral nanostructures by symmetry breaking and suggest potential applications in efficient chiral sensing, polarization detection, multimodal chiral lasing, and nonlinear optics.
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http://dx.doi.org/10.1364/OE.560511 | DOI Listing |
Bioconjug Chem
September 2025
Pôle Chimie Balard, IBMM - UMR 5247, 1919, Route de Mende, 34293 Montpellier cedex 5, France.
Phosphole-based fluorophores are attractive dyes for bioimaging due to their relatively compact molecular structures, strong fluorescence up to the near-infrared region with large Stokes shifts, and remarkable resistance to photobleaching. Therefore, the development of efficient and chemoselective coupling methods for functionalizing phospholes is of significant interest for biomolecular labeling. Herein, we describe the synthesis of novel P-aminophospholes and their use for direct conjugation to cysteinyl peptides under mild conditions.
View Article and Find Full Text PDFChaos
September 2025
Instituto de Física, Universidade Federal de Alagoas, Maceió, Alagoas 57072-970, Brazil.
Neuronal heterogeneity, characterized by a multitude of spiking neuronal patterns, is a widespread phenomenon throughout the nervous system. In particular, the brain exhibits strong variability among inhibitory neurons. Despite the huge neuronal heterogeneity across brain regions, which in principle could decrease synchronization due to differences in intrinsic neuronal properties, cortical areas coherently oscillate during various cognitive tasks.
View Article and Find Full Text PDFRSC Adv
September 2025
Laboratory of Spectroscopic Characterization and Optical Materials, Faculty of Sciences, University of Sfax B.P. 1171 3000 Sfax Tunisia
Lithium metavanadate (LiVO) is a material of growing interest due to its monoclinic 2/ structure, which supports efficient lithium-ion diffusion through one-dimensional channels. This study presents a detailed structural, electrical, and dielectric characterization of LiVO synthesized a solid-state reaction, employing X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), and impedance/dielectric spectroscopy across a temperature range of 473-673 K and frequency range of 10 Hz to 1 MHz. XRD and Rietveld refinement confirmed high crystallinity and single-phase purity with lattice parameters = 10.
View Article and Find Full Text PDFFront Oral Health
August 2025
Conservative Dentistry and Endodontics, AB Shetty Memorial Institute of Dental Sciences, Nitte (deemed to be) University, Mangalore, India.
Short-chain fatty acids (SCFAs), primarily acetate (C2), propionate (C3), and butyrate (C4), are crucial microbial metabolites formed by the fermentation of dietary fibers by gut microbiota in the colon. These SCFAs, characterized by fewer than six carbon atoms, serve as an essential energy source for colonic epithelial cells and contribute approximately 10% of the body's total energy requirement. They are central to maintaining gut health through multiple mechanisms, including reinforcing intestinal barrier function, exerting anti-inflammatory effects, regulating glucose and lipid metabolism, and influencing host immune responses.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Shaanxi Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Department of Chemistry and Chemical Engineering, ShaanXi Normal University, Xi'an, 710062, P.R. China.
Rhodamine derivatives exhibiting inverted open-closed form fluorescence behavior redefines conventional photochemical paradigms while illuminating new structure-property relationships and fascinating application potentials. Herein, we report a donor-acceptor engineering strategy that activates closed form emission in rhodamines, achieving unprecedented Stokes shifts (>280 nm) while overcoming aggregation-caused quenching. The new class of rhodamines with inverted open-close form emission behavior are created through simultaneous substitution of N,N-diethyl groups with indole (donor) and conversion of spiro-lactam to benzene sulfonamide (acceptor).
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