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This research designs and simulates a high-efficiency tandem solar cell (TSC) using SCAPS-1D (3.3.12), exploiting tandem perovskite technology for enhanced performance. The agenda of our work is here to minimize the two largest losses associated with single-junction solar cells like thermalization and transmission losses by absorbing a broader spectrum of sunlight using CsGeI/CIGS tandem solar cell technology. To ensure the accuracy of the simulated results, the authors first calibrate both the top and bottom solar cells using experimental data and compare the simulated results with experimental findings. This study investigates the impact of thickness, parasitic resistance, temperature, quantum efficiency, band diagram, absorption coefficients, and two-diode model equivalent circuit parameters on solar cell performance. This work optimizes lead-free, wide bandgap (1.6 eV) CsGeI perovskite and narrow bandgap (1.1 eV) CIGS solar cells individually and then proposes a tandem solar cell structure using a filtered spectrum approach. The proposed CsGeI/CIGS tandem solar cell device structure is studied in detail and simulated using SCAPS 1D. A tandem configuration, with a thickness of a 273 nm top cell (simulated under AM1.5G) and a 1000 nm bottom cell, achieved conversion efficiencies of 16.93% and 16.49%, respectively, with respective values of 19.31 mA cm/19.32 mA cm. By adding the voltages at same current points to make the tandem J-V curve, this design yielded a 26.06% efficient perovskite-CIGS tandem cell with of 1.73 V, of 19.32 mA cm, and FF of 77.98%. This perovskite-CIGS tandem design demonstrates a promising route for developing high-efficiency, low-cost TSCs.
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http://dx.doi.org/10.1021/acs.langmuir.5c01551 | DOI Listing |
J Phys Chem Lett
September 2025
Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87106, United States.
Defects significantly influence charge transport in CHNHPbI (MAPbI) perovskite solar cells, particularly at interfaces. Using quantum dynamics simulation, we reveal a distinct interstitial iodine (I) defect behavior at different positions in the TiO/MAPbI system. In the perovskite bulk-like region, I exhibits high mobility and dissociates detrimental iodine trimers, facilitating small-to-large polaron transition and promoting shallow trap formation.
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September 2025
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing, 100875, China.
This study presents a novel carbazole derivative functionalized with hydroxy diphosphonic acid groups (HDPACz) as an efficient annealing-free hole transport layer (HTL) through strong bidentate anchoring to indium tin oxide (ITO). Compared to conventional mono-phosphonic acid counterparts, HDPACz demonstrates superior ITO surface coverage and interfacial dipole, effectively modulating the work function of ITO. Theoretical calculations reveal enhanced adsorption energy (-3.
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September 2025
Key Laboratory of Nanosystem and Hierarchical Fabrication of Chinese Academy of Sciences, National Center for Nanoscience and Technology, Beijing, 100190, China.
All-small-molecule organic solar cells (ASM-OSCs) with completely definite chemical structure are an ideal model to establish the relationship between molecular structure and device performance via aggregates. The end-capped acceptor unit is of great significance in the regulation of aggregates by essential molecular interactions. However, the successful end-capped acceptor units for small-molecule donors have been rather poorly studied and only focused on the alkyl substituted rhodamine, limiting further development for ASM-OSCs.
View Article and Find Full Text PDFBeilstein J Nanotechnol
August 2025
Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Nuevo León. San Nicolás de los Garza, Nuevo León, 66455, México.
Nanoparticles in their pure colloidal form synthesized by laser-assisted processes such as laser ablation/fragmentation/irradiation/melting in liquids have attained much interest from the scientific community because of their specialties like facile synthesis, ultra-high purity, biocompatibility, colloidal stability in addition to other benefits like tunable size and morphology, crystalline phases, new compounds and alloys, and defect engineering. These nanocolloids are useful for fabricating different devices mainly with applications in optoelectronics, catalysis, sensors, photodetectors, surface-enhanced Raman spectroscopy (SERS) substrates, and solar cells. In this review article, we describe different methods of nanocolloidal synthesis using laser-assisted processes and corresponding thin film fabrication methods, particularly those utilized for device fabrication and characterization.
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September 2025
School of Engineering and Technology, National Textile University 37640 Faisalabad Pakistan
[This retracts the article DOI: 10.1039/D4RA01544D.].
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