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Article Abstract
We report the synthesis, plus structural and spectroscopic characterization, of a plutonium(IV) complex with the polyoxometalate WO. The complex was isolated as Cs[Pu(WO)]·CsCl·6.5HO, with the tetravalent actinide cation sandwiched between two lacunary polyoxotungstate anions. It represents a rare case of a POM compound with plutonium and also the first Peacock-Weakley type complex of plutonium.
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