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Article Abstract

Two distinct Cd metal-organic frameworks (MOFs) with the formulas {[Cd(BBZB)(oba)]·HO} (JXUST-45) and {[Cd(BBZB)(bpdc)]·2HO} (JXUST-46) featuring 2D layer and 3D pillar-layer structures, respectively, have been prepared, which were regulated by aromatic dicarboxylate ligands (4,4'-diphenyl ether dicarboxylic acid, Hoba; 4,4'-biphenyldicarboxylic acid, Hbpdc; and 4,7-bis(1-benzimidazol-1-yl)-2,1,3-benzothiazole, BBZB). JXUST-45 and JXUST-46 can be considered good fluorescence sensors toward Al, Fe, AcO, CrO, and L-serine. Meanwhile, JXUST-45 and JXUST-46 have good thermal stability and recovery ability. In addition, JXUST-45- and JXUST-46-based fluorescent test papers and light-emitting diode lamps have been further developed to realize naked-eye detection of Al, Fe, AcO, CrO, and L-serine, which has great potential for practical applications.

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http://dx.doi.org/10.1039/d5dt00305aDOI Listing

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