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This study presents a long-wave infrared (LWIR) detector based on ultrathin Type-II superlattice (T2SL) materials, which is enhanced by an M-type gold nanograting structure utilizing the metal-insulator-metal (MIM) resonant cavity effect to significantly improve light absorption and achieve broadband spectral absorption enhancement. The 14 ML InAs/7 ML GaSb T2SL material was successfully grown using molecular beam epitaxy (MBE), with its excellent crystallinity and surface morphology characterized and verified by X-ray diffraction (XRD) and atomic force microscopy (AFM). The refractive index and absorption coefficient, measured by ellipsometry, provided the required data for the subsequent finite element simulation. The simulation results show that the enhanced LWIR detector achieves peak absorption rates of 99.95% and 99.92% at wavelengths of 9.7 µm and 12.3 µm, respectively, with an average absorption rate of 96.56% across the 9.1-13.3 µm range. This design effectively avoids degradation in electrical performance caused by increased thickness during quantum efficiency (QE) optimization. Furthermore, the detector exhibits no dependence on incident angle, demonstrating significant potential for broad applications in LWIR imaging, sensing, and other advanced infrared technologies.
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http://dx.doi.org/10.1364/OE.551063 | DOI Listing |
Org Lett
September 2025
Guangdong Basic Research Center of Excellence for Aggregate Science, School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, Guangdong 518172, China.
The polymerization mechanism and the identification of key oligomer intermediates during the thermal condensation of benzoguanamine (BG) remain unclear. Herein, we report a novel mixed thermal condensation strategy using BG and a pre-synthesized dimer to selectively synthesize the trimer (BG) with a significantly enhanced yield. Comprehensive characterization techniques confirm the formation of a linear molecular structure for (BG).
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States.
Understanding how molecular aggregation influences nonlinear optical properties is essential for advancing organic fluorophores in imaging, sensing, and photonic applications. However, the relationship between the molecular aggregation and the magnitude of nonlinear two-photon absorption cross-section remains underexplored. Here, we systematically investigate the aggregation-dependent two-photon absorption properties of the fluorophore TPAPhCN by tuning the degree of aggregation.
View Article and Find Full Text PDFPlant Cell Physiol
September 2025
Biostructural Mechanism Laboratory, RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.
Phycobilisome (PBS) is a water-soluble light-harvesting supercomplex found in cyanobacteria, glaucophytes, and rhodophytes. PBS interacts with photosynthetic reaction centers, specifically photosystems II and I (PSII and PSI), embedded in the thylakoid membrane. It is widely accepted that PBS predominantly associates with PSII, which functions as the initial complex in the linear electron transport chain.
View Article and Find Full Text PDFInt J Pharm
September 2025
Department of Pharmaceutical Sciences, Via del Liceo 1, 06123 Perugia, Italy. Electronic address:
Indole-3-carboxaldehyde (I3A), a microbial tryptophan metabolite, exhibits significant immunomodulatory activity at the host-microbial interface. However, its rapid transformation into metabolites like indole-3-carboxylic acid (I3CA) raises questions about their therapeutic potential. This study aimed to evaluate the pharmacological contributions of I3CA through the development of a proper delivery strategy.
View Article and Find Full Text PDFEur J Pharm Biopharm
September 2025
Center of Drug Metabolism and Pharmacokinetics, China Pharmaceutical University, Nanjing 210009, China. Electronic address:
Prodrugs with enzymatic activation requirements, such as the weakly basic biopharmaceutical classification system (BCS) class IV compound abiraterone acetate (ABA), face considerable bioequivalence (BE) risks owing to their pH-dependent solubility, food effects, and variable intestinal hydrolysis. This study established clinically relevant dissolution specifications for ABA using biorelevant dissolution and physiologically based biopharmaceutics modelling (PBBM). Two dissolution methods, two-stage (gastrointestinal transfer simulation) and single-phase (biorelevant media), were evaluated under fasted and fed conditions.
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