Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Mechanically interlocked molecules, including catenanes, rotaxanes and knots, are an intriguing class of synthetic targets with potential applications in molecular switches and machines. Although mechanically interlocked molecules are typically constructed using macrocyclic frameworks, the interlocking of two or more three-dimensional, shape-persistent cages remains relatively underexplored. Recent advances have accelerated the development of mechanically interlocked cages (MICs), which consist of interlocked three-dimensional molecular cages rather than macrocycles. Despite their potential in areas such as molecular recognition, separation and catalysis, the design and synthesis of MICs remain challenging. This Review examines the synthetic strategies used to construct MICs, along with their interlocked architecture characteristics, structural dynamics and potential applications. Special attention is given to the guest-binding properties and catalytic performance of monomeric versus catenated cages. We conclude with perspectives on the current challenges and opportunities for future development of MICs.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1038/s41570-025-00721-7 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Comparison of compressive forces generated by dynamic compression angle-stable interlocking nail versus traditional dynamic compression plate and locking compression plate.
Res Vet Sci
September 2025
Department of Veterinary Medicine, Federal University of Jatai (UFJ), Jataí, State of Goiás, Brazil.
The aim of this study was to compare the compressive forces generated by Dynamic Compression Angle-Stable Interlocking Nail (DCASIN) with those of traditional Dynamic Compression Plates (DCP) and Locking Compression Plates (LCP) using synthetic diaphyseal bone models (SDBM). Three groups were established based on the fixation method (G-DCASIN, G-DCP, and G-LCP), with implants fixed to SDBM simulating a transverse fracture, comprising 10 repetitions per group. A strain-gauge load cell was positioned in the SDBM gap to measure compressive forces in kilograms, recorded 30 s after the completion of each group-specific compression technique.
View Article and Find Full Text PDFEffects of drying temperature, mercerizing, and coating on the properties of Colombian Coir fibers and their interfacial adhesion with polylactic acid.
Sci Rep
September 2025
Department of Mechanical Engineering, University of Cordoba, Montería, Córdoba, Colombia.
In the present study, the influence of drying temperature, mercerization, and epoxy coating on the physicochemical and mechanical properties of Colombian CFs and their interfacial adhesion with a PLA matrix were studied. CFs were extracted from the mesocarp of Cocos nucifera husks by retting. The fibers were oven-dried at two drying temperatures, 40 °C and 90 °C.
View Article and Find Full Text PDFUniform spherical chiral polyrotaxanes with steerable circularly polarized luminescence.
Nanoscale
September 2025
IGCME, PCFM Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.
Spherical chiral polyrotaxanes (CPRs) with steerable circularly polarized luminescence (CPL) are intriguing as advanced chiroptical materials but have not been reported to date. Here, we constructed spherical chiral polyrotaxane (CPR) materials with steerable CPL by utilizing cyclodextrins (α-, β-, or γ-CyD) as the chiral wheel. Importantly, the structure and the CPL performance of the CPR materials can be regulated by varying the feeding amount and the type of cyclodextrin (α-, β-, or γ-CyD).
View Article and Find Full Text PDFSoil conditioning optimization of sandy pebble soil with different fine contents and prediction by machine learning.
Sci Rep
September 2025
ShanXi First Construction Group Co., Ltd., Shanxi, 041000, China.
Proper soil conditioning is critical for earth pressure balance (EPB) shield tunneling to mitigate problems such as mud cake formation and cutter headwear by enhancing muck flow plasticity, particularly in sandy pebble soils. This research investigates the effect of conditioning agents-bentonite slurry and foam-on sandy pebble soils with varying fines contents, considering both concentration and injection ratio. Slump tests were conducted to evaluate the workability of conditioned soil.
View Article and Find Full Text PDFStereoselective Self-Assembly of a Topologically Chiral [6]Catenane with 18 Crossings.
Angew Chem Int Ed Engl
September 2025
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai, 200433, P.R. China.
Mechanically interlocked molecules (MIMs) exhibit unique properties and functions arising from their structural entanglement, features of which are absent in their individual components. However, synthesizing topologically complex architectures, particularly those with topological chirality, remains a significant challenge due to the lack of general methods for controlled entanglement. Herein, we report the stereoselective synthesis of a 24-metal-center topologically chiral [6]catenane featuring 18 crossings ( link), representing one of the most intricate MIMs constructed to date.
View Article and Find Full Text PDF