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The interaction of light with objects and media moving at relativistic and superluminal speeds enables unconventional phenomena such as Fresnel drag, Hawking radiation, and light amplification. Synthetic motion, facilitated by modulated internal degrees of freedom, enables the study of relativistic phenomena unrestricted by the speed of light. In this study, we investigate synthetically moving apertures created by high-contrast reflectivity modulations, which are generated by ultrafast laser pulses on a subwavelength thin film of indium tin oxide. The space-time diffraction of a weaker probe beam reveals a complex, non-separable spatio-temporal transformation, where changes in the frequency of the wave are correlated to changes in its momentum. By using schemes of continuous or discrete modulation we demonstrate tunable frequency-momentum diffraction patterns with gradients that depend upon the relative velocity between the modulation and the probe wave. The diffraction patterns are matched by operator-based theory and the gradients are analytically predicted using a super-relativistic Doppler model, where the modulation is described as a superluminally moving scattering particle. Our experiments open a path towards mimicking relativistic mechanics and developing complex and programmable spatio-temporal transformations of light.
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http://dx.doi.org/10.1038/s41467-025-60159-9 | DOI Listing |
Phys Rev Lett
August 2025
Universidade Federal de Pernambuco, Núcleo de Tecnologia, Centro Acadêmico do Agreste, Avenida Marielle Franco, Caruaru-PE, 55014-900, Brazil.
Self-propulsion plays a crucial role in biological processes and nanorobotics, enabling small systems to move autonomously in noisy environments. Here, we theoretically demonstrate that a bound skyrmion-skyrmion pair in a synthetic antiferromagnetic bilayer can function as a self-propelled topological object, reaching speeds of up to a hundred million body lengths per second-far exceeding those of any known synthetic or biological self-propelled particles. The propulsion mechanism is triggered by the excitation of back-and-forth relative motion of the skyrmions, which generates nonreciprocal gyrotropic forces, driving the skyrmion pair in a direction perpendicular to their bond.
View Article and Find Full Text PDFFront Bioeng Biotechnol
August 2025
The Third Department of Orthopedic Surgery, Fuxin Mining General Hospital of Liaoning Health Industry Group, Liaoning, China.
Tendon/ligament (T/L) injuries sustained during motion are highly prevalent and severely impact athletes' careers and quality of life. Current treatments, including autografts, allografts, and synthetic ligaments, have limitations such as donor site morbidity, immune rejection, and biomechanical mismatch, especially under dynamic loading conditions encountered in motion. 3D bioprinting offers a revolutionary approach for constructing patient-specific T/L grafts.
View Article and Find Full Text PDFAdv Mater
September 2025
Institute for Bioengineering of Catalonia (IBEC), Barcelona Institute of Science and Technology (BIST), Carrer de Baldiri i Reixac, 10-12, Barcelona, 08028, Spain.
Active matter, encompassing both natural and artificial systems, utilizes environmental energy to sustain autonomous motion, exhibiting unique non-equilibrium behaviors. Artificial active matter (AAM), such as nano/micromotors, holds transformative potential in precision medicine by enhancing drug delivery and enabling targeted therapeutic interventions. Under the demand for increasing intelligence in AAM, controlling their non-equilibrium processes within complex in vivo environments presents significant challenges.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
CFisUC, Department of Physics, University of Coimbra, 3004-516, Coimbra, Portugal.
With the goal of manipulating (bio)chemical processes, photoswitches emerge as important assets in molecular nanotechnology. To guide synthetic strategies toward increasingly more efficient systems, conformational dynamics studies performed with atomic rigor are in demand, particularly if this information can be extracted with control over the size of a perturbing solvation layer. Here, we use jet-cooled rotational spectroscopy and quantum chemistry calculations to unravel the structure and micro-hydration dynamics of a prototype photoswitch.
View Article and Find Full Text PDFChem Sci
August 2025
College of Chemistry and Chemical Engineering, Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang University Jiujiang 332005 China
BN-fused aromatic compounds have garnered significant attention due to their unique electronic structures and exceptional photophysical properties, positioning them as highly promising candidates for applications in organic optoelectronics. However, the regioselective synthesis of BN isomers remains a formidable challenge, primarily stemming from the difficulty in precisely controlling reaction sites, limiting structural diversity and property tunability. Herein, we propose a regioselective synthetic strategy that employs 2,1-BN-naphthalene derivatives, wherein selective activation of N-H and C-H bonds is achieved in conjunction with -halogenated phenylboronic acids.
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