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Billions of years ago, Mars' ability to sustain liquid water waned as the solar wind and radiation began to erode the atmosphere. Sputtering is an atmospheric escape process that may have been dominant during earlier epochs of our Sun according to isotopic evidence, but is difficult to detect under current solar conditions. Using over 9 years of data from the Mars Atmosphere and Volatile Evolution mission, we present the first observations of present-day sputtering in the martian upper atmosphere. By correlating argon densities with solar electric fields, we find that sputtered rates of argon are over four times higher than model predictions. We also present evidence of enhanced sputtering during a solar storm, offering a glimpse at more intense conditions in the early solar system. Observationally establishing the role of sputtering in the loss of Mars' atmosphere is critical to understanding the conditions that allowed liquid water to exist on the martian surface and the implications for habitability.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12118633 | PMC |
http://dx.doi.org/10.1126/sciadv.adt1538 | DOI Listing |
Nanoscale
September 2025
Department of Physics, University of Oxford, Parks Road, Oxford, OX1 3PU, UK.
The mechanical properties of the polymeric substrate or matrix where a cell grows affect cell behavior. Most studies have focused on relating elastic properties of polymeric substrates, which are time-independent, to cell behaviors. However, polymeric substrates and biological systems exhibit a time-dependent, often viscoelastic, mechanical response.
View Article and Find Full Text PDFChembiochem
September 2025
Department of Food, Environmental and Nutritional Sciences (DeFENS), University of Milan, via Mangiagalli 25, 20133, Milan, Italy.
This study investigates the synthesis of aromatic nitriles using an evolved variant of OxdF1 (L318F/F306Y), an aldoxime dehydratase from Pseudomonas putida F1, engineered for improved catalytic efficiency toward benzaldehyde oxime. The double OxdF1 (L318F/F306Y) mutant effectively catalyzes the conversion of various benzaldoxime derivatives to the corresponding nitriles. Due to the enzyme's inherent instability, immobilized whole-cell systems are employed in a flow reactor to improve its stability and broaden its applicability, with the biotransformation of benzaldehyde oxime and 2,6-difluorobenzaldehyde oxime serving as case studies.
View Article and Find Full Text PDFChemistry
September 2025
Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, Adelaide, South Australia, 5042, Australia.
2D Bismuth oxycarbonate (2D BOC) nanosheets have a unique layered structure with many applications, including capture and reduction of carbon dioxide. Processing powdered elemental bismuth in water under ambient air conditions using a vortex fluidic device (VFD) results in the formation of 2D BOC without the need of surfactants or other excipients. The induced high shear mechanical energy in the form of micron/submicron topological typhoon like spinning top (ST) fluid flow drives the conversion, which we propose initially melts the metal particles which are spontaneously oxidised at the liquid-quartz tube interface to form 2D bismuth oxide (BiO).
View Article and Find Full Text PDFJ Sep Sci
September 2025
Programa De Pós-Graduação em Química, Universidade Federal de Sergipe, São Cristóvão, Sergipe, Brazil.
Secondary metabolites are important bioactive compounds for diet and medicine. This study optimizes the extraction of hydroethanolic herbal extracts using an EDGE (Energized Dispersive Guided Extraction) system, evaluates their antioxidant capacity, and analyzes correlations among antioxidant activity, total phenolic content, and individual compounds. A Doehlert matrix design was used to optimize extraction, having temperature and time as independent variables, and total phenolic content (mg GAE/g) as the response, quantified via the Folin-Ciocalteu method.
View Article and Find Full Text PDFBiomed Chromatogr
October 2025
Department of Pharmaceutical Analysis, Pharmacy School, Shenyang Pharmaceutical University, Shenyang, China.
A rapid and specific liquid chromatography-tandem mass spectrometry method with a wide linear range was developed and validated for the simultaneous quantification of Vitamin K1 (VK1) trans- and cis- isomers in human plasma. Bovine serum albumin solution (15%) served as a surrogate matrix for preparing the calibrators to establish the quantitative curves. After liquid-liquid extraction, VK1 trans- and cis- isomers in plasma samples were separated on a ChromCore C30 column (15 cm × 4.
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