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Nonvolatile photonic integrated circuits employing phase change materials have relied either on optical switching with precise multi-level control but poor scalability or electrical switching with seamless integration and scalability but mostly limited to a binary response. The main limitation of the latter is relying on stochastic nucleation, since its random nature hinders the repeatability of multi-level states. Here, we show engineered waveguide-integrated microheaters to achieve precise spatial control of the temperature profile (i.e., hotspot) and, thus, switch deterministic areas of an embedded phase change material. We experimentally demonstrate this concept using a variety of foundry-processed doped-silicon microheaters on a silicon-on-insulator platform featuring SbSe or GeSbSeTe and achieve 27 cycles with 7 repeatable levels each. We further characterize the microheaters' response using Transient Thermoreflectance Imaging. Our microstructure engineering concept demonstrates the evasive repeatable multi-levels employing a single microheater device, which is necessary for robust and energy-efficient reprogrammable phase change photonics in analog processing and computing.
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http://dx.doi.org/10.1038/s41467-025-59399-6 | DOI Listing |
J Phys Chem B
September 2025
Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh 208016, India.
Understanding the evaporation mechanism of liquid ethanol and ethanol-water binary mixtures is important for numerous scientific and industrial processes. The amount of water in liquid water-ethanol mixtures can significantly affect how quickly ethanol molecules evaporate. Here, we study the mechanism and rate of evaporation of ethanol from pure liquid ethanol and ethanol/water binary mixtures through both unbiased molecular dynamics simulations and biased simulations using the umbrella sampling method.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
National Engineering Research Center of Lower-Carbon Catalysis Technology, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Zeolite-confined Rh-based catalysts have emerged as promising heterogeneous candidates for olefin hydroformylation. However, they face challenges of reactant- and product-induced Rh leaching and aggregation. Herein, zeolite framework-anchored Rh-(O-Zn) sites were designed and are shown to have remarkable activity and stability for gas-phase ethylene hydroformylation.
View Article and Find Full Text PDFAnn Am Thorac Soc
September 2025
University of Florida, Department of Medicine, Gainesville, Florida, United States;
Background: Pulmonary hypertension (PH) is a systemic illness with increasingly subtle disease manifestations including sleep disruption. Patients with PH are at increased risk for disturbances in circadian biology, although to date there is no data on "morningness" or "eveningness" in pulmonary vascular disease.
Research Questions: Our group studied circadian rhythms in PH patients based upon chronotype analysis, to explore whether there is a link between circadian parameters and physiologic risk-stratifying factors to inform novel treatment strategies in patients with PH?
Study Design And Methods: We serially recruited participants from July 2022 to March 2024, administering in clinic the Munich Chronotype Questionnaire (MCTQ).
Phys Rev Lett
August 2025
Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.
We have observed the signatures of valence electron rearrangement in photoexcited ammonia using ultrafast hard x-ray scattering. Time-resolved x-ray scattering is a powerful tool for imaging structural dynamics in molecules because of the strong scattering from the core electrons localized near each nucleus. Such core-electron contributions generally dominate the differential scattering signal, masking any signatures of rearrangement in the chemically important valence electrons.
View Article and Find Full Text PDFPhys Rev Lett
August 2025
European Laboratory for Non Linear Spectroscopy (LENS), Istituto Nazionale di Ottica, Consiglio Nazionale delle Ricerche (CNR-INO), via Nello Carrara 1, 50019 Sesto Fiorentino, Italy and , via Nello Carrara 1, 50019 Sesto Fiorentino, Italy.
Single crystal x-ray diffraction measurements have been carried out on epsilon oxygen up to 30 GPa to examine the behavior of the constituent (O_{2})_{4} units. An isostructural phase transition is evidenced by lattice parameter and intracluster (O_{8}) distance discontinuities and clear changes in the equation of state at 18.1±0.
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