Fluorescent Molecular Imprinted Sensor Based on Carbon Quantum Dot for Nitrofen Detection in Water Sample.

The structure of nitrofen is stable and resistant to natural degradation, persisting in environments for extended periods. It can accumulate through the food chain, posing risks to human health. Here, we report a sensor based on carbon quantum dots (CQDs) and molecular imprinting technology (CQDs@MIPs). It not only possesses the specificity and stability of MIPs but also incorporates the environmental friendliness and signal amplification capabilities of CQDs, making it an ideal material for the specific detection of nitrofen residues in the environment. The interaction between CQDs@MIPs and nitrofen, as well as the successful removal of nitrofen, were confirmed through transmission electron microscopy (TEM) and Zeta potential analysis, which evaluated the morphology and particle size of the prepared CQDs@MIPs. After binding with nitrofen, the CQDs@MIP sensor exhibited a low detection limit (2.5 × 10 mg·L), a wide detection range (0.01-40 mg·L), a good linear relationship (R = 0.9951), and a short detection time (5 min). The CQDs@MIP sensor also demonstrated excellent stability, with the fluorescence intensity of CQDs@MIPs remaining above 90% of the initial preparation after 20 days. At the same time, Red, Green, Blue (RGB) color model extraction technology is used to fit the color of the sample under different concentrations, and the smart phone application is integrated to realize the visual detection of nitrofen. Furthermore, acceptable accuracy was achieved in real water samples (recovery rates ranging from 84.1% to 115.7%), indicating that our CQDs@MIP sensor has high analytical potential for real samples.