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Article Abstract
Herein, we report the synthesis and characterization of novel (P^N) aryl Au(III)-azide complexes. The reductive elimination from these Au(III) complexes to forge C(sp)-N bonds has also been demonstrated. Considering the feasibility of C(sp)-N reductive elimination in Au(III)-azide complexes, the gold-catalyzed C(sp)-N cross-coupling reaction has been achieved. Furthermore, it is shown that the Au(III)-azide complexes undergo facile azide exchange with cyano and alkyne nucleophiles, facilitating C(sp)-C(sp) cross-coupling.
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| http://dx.doi.org/10.1039/d5cc01179e | DOI Listing |
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