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A wave energy converter (WEC) utilizing the inertial gyroscope coupled with a hydraulic power take-off (PTO) unit for energy transformation and application is investigated. The structure design of various components of WEC are introduced. Power is obtained by the dynamic response of the floating body under the excitation of wave energy, and converted into gyroscopic precession in the form of swing angle and torque, and directly to drive the hydraulic pump module of the hydraulic PTO system to output the hydraulic energy. The fluctuation of pressure and flow in the hydraulic PTO system can be adjusted and smoothed by means of the accumulator, which can effectively improve power output stationarity of the hydraulic motor-generator. The mathematical models of energy conversion and transmission process encompassing the wave-to-hydraulic PTO unit are established. The impact rules of major variables in the gyroscope and hydraulic PTO unit acting on WEC system are investigated by numerical simulations. It can provide scientific basis for optimizing utilization of this wave energy conversion system, and provide mathematical guidance for the optimization control of the WEC system. To improve the computation real time and control precision of power output of the hydraulic motor-generator unit, an Adaptive Hierarchical Model Predictive Control (AHMPC) method is proposed and put into used. The AHMPC strategy utilizes a larger wave prediction sequence level to solve the offline unconstrained energy maximization control problem, and then a smaller level to deal with the online constraints. The AHMPC method saves 3 times the computation time compared to the traditional MPC method, reduces the energy fluctuation amplitude in the system by 96%, so that the hydraulic motor-generator can operate at the desired speed based on the available wave forecast information while satisfying the state constraints.
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http://dx.doi.org/10.1038/s41598-025-91953-6 | DOI Listing |
Inorg Chem
September 2025
Synthesis and Characterization of Innovative Materials, TUM School of Natural Sciences, Department of Chemistry, Technical University of Munich, Lichtenbergstraße 4, Garching b. München 85748, Germany.
Semiconductors with one-dimensional (1D) substructures are promising for next-generation optical and electronic devices due to their directional transport and flexibility. Representatives of this class include HgPbP-type materials. This study investigates the related semiconductors AgGeP and AgSnP.
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September 2025
Institute of Theoretical Chemistry, Faculty of Chemistry, University of Vienna, Währinger Straße 17, 1090 Vienna, Austria.
We present a novel, flexible framework for electronic structure interfaces designed for nonadiabatic dynamics simulations, implemented in Python 3 using concepts of object-oriented programming. This framework streamlines the development of new interfaces by providing a reusable and extendable code base. It supports the computation of energies, gradients, various couplings─like spin-orbit couplings, nonadiabatic couplings, and transition dipole moments─and other properties for an arbitrary number of states with any multiplicities and charges.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
Shock Wave Research Laboratory, Department of Physics, Abdul Kalam Research Center, Sacred Heart College (Autonomous), affiliated to Thiruvalluvar University, Tirupattur, Tamil Nadu, 635 601, India.
Bismuth ferrite (BiFeO) is a semiconductor with multiferroic properties, synthesized by the sol-gel method. While static high-pressure studies have advanced our understanding of the phase behavior of BiFeO, the effects of dynamic pressure acoustic shock waves remain unexplored. In this study, BiFeO was subjected to 100 shock pulses with 0.
View Article and Find Full Text PDFResearch (Wash D C)
September 2025
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan 250061, China.
With the rapid advancement of communication technologies, issues of electromagnetic pollution and electromagnetic compatibility have become increasingly severe, heightening the demand for high-performance electromagnetic wave absorption materials. Metal-organic frameworks (MOFs) have flourished in this field owing to their chemical tunability, high porosity, tailored topological structures, and functionality. MOF-derived composites exhibit diverse loss mechanisms and heterogeneous structures, achieving lightweight, broadband, and highly efficient absorption.
View Article and Find Full Text PDFChemphyschem
September 2025
Institute of Physics, Polish Academy of Sciences, PL-02-668, Warsaw, Poland.
B,N-substituted graphene ribbons are computationally designed and their spectroscopic properties are systematically explored with wave-function-based electronic structure methods. All B,N-graphene ribbons exhibit exceptionally small S-T energy gaps. The oscillator strength of the S-S transition increases monotonically with the length of the ribbons.
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