One-dimensional convolutional neural network-based analysis of dielectric spectral abundance in liquid-phase media.

Sci Rep

College of Water Conservancy and Construction Engineering, Northwest Agricultural and Forestry University, Xianyang, 712100, Yangling, People's Republic of China.

Published: March 2025


Category Ranking

98%

Total Visits

921

Avg Visit Duration

2 minutes

Citations

20

Article Abstract

Aiming at the difficult problem of component information analysis of mixed dielectric spectra, the component information characteristics of mixed dielectric spectra are investigated by one-dimensional convolutional neural network, and the component analysis of mixed media is realised. First, the mixed dielectric spectra of water, ethanol and isopropoxyethano (iso) with different volume ratios were obtained by experimental measurements, and the singular spectrum analysis (SSA) method was applied to denoise the raw data, which provides a new data processing method for the effective analysis of dielectric spectra. Then, Utilizing the linear mixing model, we systematically obtained the dielectric spectra of binary mixtures of pure water and isopropoxyethanol with diverse ratios, along with those of multi-component mixtures integrating water, ethanol, and isopropoxyethanol at various proportion settings. The generated data were used as a training set for a one-dimensional convolutional neural network to model the correlation between the mixed dielectric spectra and the mixing ratios. The coefficient of determination (R) values of the model for the two-component and three-component mixed solution test sets were both found to be 0.999. In the validation sets, the corresponding R² values were determined to be 0.9887 and 0.9786, indicating that the accuracy and reliability of the unmixing algorithm based on the one-dimensional convolutional neural network in predicting the dielectric spectra of different proportions of the mixed media are good. This study provides an effective method to analyse and predict the dielectric properties of mixed media integrated apparent dielectric spectra, which provides a scientific basis for the research and analysis of the dielectric properties of mixed media, in addition to this study, this study promotes the integration of dielectric spectroscopy analysis and machine learning, providing new ideas and tools for the research of water environment governance and hydrochemical analysis.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11876443PMC
http://dx.doi.org/10.1038/s41598-025-86667-8DOI Listing

Publication Analysis

Top Keywords

dielectric spectra
32
one-dimensional convolutional
16
convolutional neural
16
mixed dielectric
16
mixed media
16
dielectric
12
analysis dielectric
12
neural network
12
mixed
9
analysis
8

Similar Publications

In this paper, we investigated the thermal, dynamical, and structural properties, as well as association patterns, in 3-phenyl-1-propanol (3P1Pol) and 3-phenyl-1-propanal (3P1Pal), with special attention paid to the latter compound. Both systems turned out to be good glass formers, differing by 17 K in the glass transition temperature, which indicated a strong change in the self-assembly pattern. This supposition was further confirmed by the analysis of dielectric spectra, where, apart from the α-relaxation, also a unique Debye (D)-mode, being a fingerprint of the self-association, characterized by different dynamical properties (dielectric strength, timescale separation from the α-process), was detected in both samples.

View Article and Find Full Text PDF

Coupling electrochemical and spectroscopic methods for river water dissolved organic matter characterization.

Environ Monit Assess

September 2025

Department of Environmental Chemistry, IDAEA-CSIC, Jordi Girona 18-26, 08034, Barcelona, Spain.

Monitoring dissolved organic matter (DOM) in surface waters is essential for assessing ecosystem health and detecting pollution. However, conventional spectroscopic techniques often provide limited information about the electrochemical behavior of DOM. This study integrates electrochemical impedance spectroscopy (EIS) with classical methods such as UV-Vis absorption and fluorescence spectroscopies to improve DOM characterization in river water samples.

View Article and Find Full Text PDF

Alloying AlN with ScN provides a robust strategy for engineering its intrinsic bandgap, phonons and dielectric functions, and ScAlN alloys have demonstrated great promise in applications including the 5G mobile network, surface acoustic wave devices and nanophotonics. Sc doping has been shown to greatly influence the phonons and infrared dielectric functions of AlN, yet few studies have focused on its influence on surface phonon polaritons, which are crucial to modulating the radiative properties of ScAlN metasurfaces. Herein, we combined first-principles and finite element method (FEM) simulations to fully investigate the effects of Sc incorporation on the phonon dispersion relation, propagation and localization of SPhPs and the modulated radiative properties of ScAlN nanoresonators.

View Article and Find Full Text PDF

Synthesis of Tetragonal BaTiO Nanoparticles in Methanol.

Nanomaterials (Basel)

August 2025

Department of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, 01069 Dresden, Germany.

BaTiO (BT) is an essential material for many applications due to its dielectric, ferroelectric, and piezoelectric properties; nevertheless, it has been reported to possess a "critical size" in the nanoscale below which its outstanding properties are lost and the paraelectric cubic phase is stabilized at room temperature instead of the tetragonal phase. This value depends on multiple factors, mostly resulting from the synthesis route and conditions. Especially, internal stresses are known to promote the loss of tetragonality.

View Article and Find Full Text PDF

Molecular fluctuations in mixed-metal MOF-74: influence of the metal composition.

RSC Adv

August 2025

Bundesanstalt für Materialforschung und -prüfung (BAM) Unter Den Eichen 87 12205 Berlin Germany +49 30/8104-73384 +49 30/8104-3384.

A selected series of metal-organic frameworks M-MOF-74 (M = Mg, Co, Ni) and mixed metal MM-MOF-74 (Mg/Co or Mg/Ni) with different compositions of metal atoms have been prepared and further investigated by broadband dielectric spectroscopy (BDS) in a wide temperature range. The dielectric spectra show at least two relaxation processes. Process-A is observed only for the Ni-containing MOFs and is attributed to localized fluctuations of the metal oxide corners.

View Article and Find Full Text PDF