Enhanced Hydrogen Evolution Reaction Using Biomass-Activated Carbon Nanosheets Derived from Eucalyptus Leaves.

Carbonaceous-based metal-free catalysts are promising aspirants for effective electrocatalytic hydrogen generation. Herein, we synthesized mesoporous-activated carbon nanosheets (ELC) from biomass leaves through KOH activation. The microstructure, structural, and textural characteristics of the prepared materials were characterized by FE-SEM, Raman, XRD, and BET measurements. The high temperature (700 °C) KOH-activated ELC nanosheets exhibited an interconnected nanosheet morphology with a large specific surface area (1436 m/g) and high mesoporosity. The ELC-700 catalyst exhibited an excellent electrocatalytic HER performance with a low overpotential (39 mV at 10 mA/cm), excellent durability, and a Trivial Tafel slope (36 mV/dec) in 0.5 M HSO electrolyte. These findings indicate a new approach for developing excellent biomass-derived electrocatalysts for substantially efficient green hydrogen production.