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Copper mining drives economic growth, with the global demand expected to reach 120 million metric tons annually by 2050. However, mining produces tailings containing heavy metals (HMs), which poses environmental risks. This study investigated the efficacy of phytoremediation (Phy) combined with electrokinetic treatment (EKT) to increase metal uptake in grown in tailings from the Metropolitan Region of Chile. The plants were exposed to varying voltages and treatment durations. In the control (no EKT), the root metal contents were Fe (1008.41 mg/kg) > Cu (176.38 mg/kg) > Mn (103.73 mg/kg) > Zn (30.26 mg/kg), whereas in the shoots, the order was Mn (48.69 mg/kg) > Cu (21.14 mg/kg) > Zn (17.67 mg/kg) > Fe (27.32 mg/kg). The optimal EKT (15 V for 8 h) significantly increased metal uptake, with roots accumulating Fe (5997.24 mg kg) > Mn (672 mg kg) > Cu (547.68 mg kg) > Zn (90.99 mg kg), whereas shoots contained Fe (1717.95 mg kg) > Mn (930 mg kg) > Cu (219.47 mg kg) > Zn (58.48 mg kg). Although EKT enhanced plant growth and biomass, higher voltages stressed the plants. Longer treatments were more effective, suggesting that EK-Phy is a promising method for remediating metal-contaminated tailings.
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http://dx.doi.org/10.3390/toxics12120860 | DOI Listing |
J Am Chem Soc
September 2025
Department of Chemical Engineering, National Taiwan University, Taipei 106319, Taiwan.
To address the increasingly limited water availability, using metal-organic frameworks (MOFs) to capture atmospheric water vapor as usable resources has emerged as a promising strategy. The adsorption characteristics of MOFs as well as their step pressure (i.e.
View Article and Find Full Text PDFChemistryOpen
September 2025
CMC UMR 7140, CNRS, Université de Strasbourg, Strasbourg, F-67000, France.
Two series of robust pillared metal-organic frameworks (MOFs) are obtained under solvothermal conditions by combining a metal salt with either Hbpdc, biphenyl-4,4'-dicarboxylic acid, or Hpda, 1,4-phenylenediacrylic acid, forming 2D layers, which are pillared by L, an alloxazine derivative of 1,4-di(pyridin-4-yl)benzene using a one-pot three-component strategy. Crystallographic studies reveal the formation of two isomorphous series of compounds, namely 1-M (from Hbpdc with M = Co, Ni, Cu, and Zn) and 2-M (from Hpda with M = Co or Cu). The multifunctional compounds have high decomposition temperatures, and their sorption properties were measured, revealing relatively low surface areas.
View Article and Find Full Text PDFJ Environ Manage
September 2025
Zhejiang Collaborative Innovation Center for Full-Process Monitoring and Green Governance of Emerging Contaminants, Key Laboratory of Pollution Exposure and Health Intervention of Zhejiang Province, Interdisciplinary Research Academy (IRA), Zhejiang Shuren University, Hangzhou, 310015, China. Electr
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View Article and Find Full Text PDFEcotoxicol Environ Saf
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Key Laboratory of Environment Remediation and Ecological Health, Ministry of Education, College of Environmental & Resource Science, Zhejiang University, Hangzhou 310058, China; Zhejiang Provincial Key Laboratory of Subtropic Soil and Plant Nutrition, Zhejiang University, Hangzhou 310058, China. Ele
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View Article and Find Full Text PDFEcotoxicol Environ Saf
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Department of Agricultural Biotechnology, College of Agriculture and Life Sciences, Seoul National University, Seoul 08826, Republic of Korea; Department of Applied Biology and Chemistry, College of Agriculture and Life Sciences, Seoul National University, Seoul 08826, Republic of Korea; Research In
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