2D Carbon-Anchored Platinum-Based Nanodot Arrays as Efficient Catalysts for Methanol Oxidation Reaction.

Ultrafine Pt-based alloy nanoparticles supported on carbon substrates have attracted significant attention due to their catalytic potential. Nevertheless, ensuring the stability of these nanoparticles remains a critical challenge, impeding their broad application. In this work, novel nanodot arrays (NAs) are introduced where superfine alloy nanoparticles are uniformly implanted in a 2D carbon substrate and securely anchored. Electrochemical testing of the PtCo NAs demonstrates exceptional methanol oxidation reaction (MOR) activity, achieving 1.25 A mg. Moreover, the PtCo NAs exhibit outstanding stability throughout the testing period, underscoring the effectiveness of the anchoring mechanism. Comprehensive characterization and theoretical calculations reveal that the 2D carbon-anchored structure optimizes the electronic structure and coordination environment of Pt, restricts nanoparticle migration, and suppresses transition metal dissolution. This strategy represents a major advancement in addressing the stability limitations of ultrafine nanoparticles in catalytic applications and offers broader insights into the design of next-generation catalysts with enhanced durability and performance.