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The durability and mechanical properties of synthetic medical gloves, such as those made from nitrile, vary drastically depending on the manufacturer. This study reports the chemical composition of several brands of nitrile gloves via FTIR and solid-state NMR analysis and relates composition to glove durability (found via GAD), mechanical performance (found via Instron), and whether the gloves meet or fail ASTM International standards. Out of the four nitrile examination glove brands tested, American Nitrile Slate brand had superior durability results and was found to be made of acrylonitrile butadiene rubber, as expected. The U.S. Medical glove brand, which was also found to be pure nitrile, had the superior tensile results, consistently reaching over 800% elongation before breaking. Although Restore Touch brand exam gloves were made of nitrile, they exhibited substandard tensile strength and durability due to the thinness of the glove, which barely met the ASTM minimum thickness value. The Vglove brand glove had the overall worst mechanical properties, did not meet ASTM requirements, and had an NMR spectrum consistent with that of a polyvinyl chloride glove, rather than nitrile. Gloves that fail to meet the minimum performance requirements should not be used for medical purposes to protect the health and safety of consumers.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11527158 | PMC |
http://journals.plos.org/plosone/article?id=10.1371/journal.pone.0312891 | PLOS |
Sci Justice
September 2025
Department of Police Administration, Daegu University, PO Box 38453, Daegu, South Korea; Department of Policing & Security, Rabdan Academy, PO Box 114646, Abu Dhabi, United Arab Emirates. Electronic address:
Latent fingermark recovery from beverage containers is an important aspect of forensic investigations, yet the influence of substrate properties and beverage temperatures on fingermark development remains understudied. This exploratory study assessed the development and quality of latent fingermarks on disposable beverage cups made of nonporous plastic and semiporous paper using cyanoacrylate (CA) fuming, under conditions approximating a typical café environment. A total of 255 cups (107 plastic, 148 paper) were collected after participants consumed hot and iced beverages in a controlled classroom setting.
View Article and Find Full Text PDFJ Org Chem
September 2025
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St, Irkutsk 664033, Russian Federation.
In this work, the superbase-mediated self-organization of tetrasubstituted pyrroles from three molecules of acetylenes and one molecule of nitriles was theoretically investigated. On the example of interaction of phenylacetylene with benzonitrile in the KOBu/DMSO medium, three possible pathways of the assembly of 2-benzyl-3,5-diphenyl-4-phenylethynyl-1-pyrrole have been studied using a combined B2PLYP-D3/6-311+G**//B3LYP-D3/6-31+G* quantum chemical approach. The calculated activation barriers correspond to mild reaction conditions (room temperature for 15 min).
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
University of Coimbra, CQC-IMS, Department of Chemistry, 3004-535 Coimbra, Portugal.
2-Aminooxazole 1 is a key intermediate in plausible prebiotic pathways to activated pyrimidine ribonucleotides. However, its photochemistry and underlying reaction mechanism remain unclear. Here, we present a combined matrix-isolation infrared spectroscopic and computational investigation of the UV-induced photochemistry of 1.
View Article and Find Full Text PDFOrg Lett
September 2025
Graduate School of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka 812-8582, Japan.
We report Lewis acid-catalyzed direct conversion of carboxylic acids into primary amides and nitriles using bis(trimethylsilyl)amine as an ammonia surrogate. With 1.1 equiv of bis(trimethylsilyl)amine, ytterbium(III) and hafnium(IV) triflates efficiently catalyzed the reaction, affording various primary amides in high yields with a broad substrate scope.
View Article and Find Full Text PDFJMIR Res Protoc
September 2025
Service of Clinical Pharmacology, Department of Medicine, Lausanne University Hospital and University of Lausanne, Lausanne, Switzerland.
Background: Janus kinase inhibitors (JAKIs) are small molecules used orally to treat inflammatory and hematological disorders. They have demonstrated impressive efficacy across multiple indications. However, concerns have emerged regarding their safety profile.
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