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Two-dimensional materials show great potential for future electronics beyond silicon materials. Here, we report an exotic multiple-port device based on multiple electrically tunable planar p-n homojunctions formed in a two-dimensional (2D) ambipolar semiconductor, tungsten diselenide (WSe). In this device, we prepare multiple gates consisting of a global gate and several local gates, by which electrostatically induced holes and electrons are simultaneously accumulated in a WSe channel, and furthermore, at the boundaries, p-n junctions are formed as directly visualized by Kelvin probe force microscopy. Therefore, in addition to the gate voltages in our device, the drain/source bias can also be used to switch the 2D WSe channel on/off due to the rectification effect of the formed p-n junctions. More importantly, when the voltage on the global gate electrode is altered, all p-n junctions are affected, which makes it possible to perform parallel logic operations.
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http://dx.doi.org/10.1021/acs.nanolett.4c04337 | DOI Listing |
ACS Nano
September 2025
School of Microelectronics, University of Science and Technology of China, Hefei, Anhui 230026, China.
Superlinear photodetectors hold significant potential in intelligent optical detection systems, such as near-field imaging. However, their current realization imposes stringent requirements on photosensitive materials, thereby limiting the flexibility of the device integration for practical applications. Herein, a tunable superlinear GaO deep-ultraviolet gate-all-around (GAA) phototransistor based on a p-n heterojunction has been proposed.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Institute of Semiconductor Electronics (IHT), RWTH Aachen University, 52074 Aachen, Germany.
Hard entropy limits of impurity doping prevent further miniaturization of low nanoscale silicon-based very large scale integration (VLSI) devices, thereby obstructing the path toward more energy-efficient VLSI designs with higher yield in compute power. As demonstrated here by synchrotron UV photoelectron spectroscopy (UPS) and X-ray absorption spectroscopy in total fluorescence yield mode (XAS-TFY), intrinsic Si at the bottom of the nanoscale (i-nano-Si) turns into strong p- or n-Si by embedding in silicon nitride (SiN) or silicon dioxide (SiO), respectively. The associated Nanoscale Electronic Structure Shift Induced by Anions at Surfaces (NESSIAS) creates a p/n junction in i-nano-Si by the quantum-chemical impact of SiN- vs SiO-coating, providing energy landscapes to accumulate electrons (holes) when SiO- (SiN-) coated, with free charge carriers provided by metallic interconnects.
View Article and Find Full Text PDFJ Phys Condens Matter
August 2025
Department of Physics, Humboldt-Universität zu Berlin, Newtonstraße 15, Berlin, Berlin, 12489, GERMANY.
The continuous miniaturization of semiconductor nanodevices necessitates advanced characterization techniques to probe their internal electrostatic potential under operational conditions. Off-axis electron holography (EH) enables quantitative mapping of phase shifts induced by electrostatic potentials, yet its application in operando transmission electron microscopy (TEM) is hindered by focused ion beam (FIB)-induced surface artifacts, such as amorphized layers and charge trapping, which distort the potential landscape, in addition to long-range electric stray fields. This study introduces an extended multilayer framework to efficiently model 3D electrostatic potential distributions in such FIB-prepared TEM-lamellae.
View Article and Find Full Text PDFPhotochem Photobiol Sci
August 2025
Department of Chemistry, School of Basic Sciences, Swami Vivekananda University, Kolkata, 700121, India.
Sensitization of wide bandgap semiconductors by coupling with a low-band-gap semiconductor to improve photoinduced charge carrier separation by the built-in electric field is one of the attractive approaches to develop an efficient photocatalyst. Here we present the development of Ag-ZnMnO/exfoliated g-CN (Ag-ZMO/ECN), a novel photocatalyst designed to remove an inorganic pollutant Cr(VI) under direct solar light irradiation. The enhanced performance of Ag-ZMO/ECN is attributed to efficient charge separation, facilitated by the formation of a p-n junction at the interface of narrow-bandgap p-type ZMO and n-type ECN, and the localized surface plasmon resonance (LSPR) effect of the deposited Ag nanoparticles.
View Article and Find Full Text PDFAnal Chem
September 2025
School of Advanced Technology, Xi'an Jiaotong─Liverpool University, 215123 Suzhou, China.
Metal organic frameworks (MOFs), crystalline solids consisting of organic ligands and metal ions, have attracted increasing interest in various areas, including catalysis and biology. Functionalizable pore interiors and ultrahigh surface-to-volume ratios of MOFs make them excellent materials, especially for surface-enhanced Raman scattering (SERS) by the photoinduced charge transfer (PICT) between the MOFs and adsorbed molecules for SERS signal amplification. In our previous work, we demonstrated a p-n junction-assisted MOF substrate for enhancing the SERS signal through additional charge transfer, while the notable structural characteristics of MOFs benefit the SERS selectivity.
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