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Driving spin systems to states far from equilibrium is indispensable in investigations of functional nonlinearities of antiferromagnets for spintronics. So far, it has been shown that electric-field pulses in the spectral region from the visible to the terahertz range can be used to induce ultrafast switching between different spin states. Here we demonstrate that a multicycle terahertz magnetic-field pulse can be used to induce non-thermal spin switching in antiferromagnets. When a strong pulse is applied to SmErFeO, the magnetic order parameter is first driven away from the barrier between the two potential minima of this antiferromagnet and then, in the subsequent inertial motion towards the opposite direction, it crosses the barrier. Our analysis reveals that the initial motion is driven by a dynamical modification of the magnetic potential, and this modification is enhanced through coupling between the two magnon modes.
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http://dx.doi.org/10.1038/s41563-024-02034-4 | DOI Listing |
Adv Mater
September 2025
College of Physics, Donghua University, Shanghai, 201620, China.
The 180° switching of the perpendicular Néel vector induced by the spin-orbit torque (SOT) presents significant potential for ultradense and ultrafast antiferromagnetic SOT-magnetoresistive random-access memory. However, its experimental realization remains a topic of intense debate. Here, unequivocal evidence is provided for the SOT-induced 180° switching of the perpendicular Néel vector in collinear antiferromagnetic CrO in a Pt/CrO/Co trilayer structure.
View Article and Find Full Text PDFNat Commun
September 2025
Physikalisches Institut, Karlsruhe Institute of Technology, Karlsruhe, Germany.
Precise control of spin states and spin-spin interactions in atomic-scale magnetic structures is crucial for spin-based quantum technologies. A promising architecture is molecular spin systems, which offer chemical tunability and scalability for larger structures. An essential component, in addition to the qubits themselves, is switchable qubit-qubit interactions that can be individually addressed.
View Article and Find Full Text PDFChem Sci
August 2025
Department of Chemistry, University of Pennsylvania 231 South 34th Street Philadelphia PA 19104 USA
Using an Earth-abundant transition metal to mediate formation and splitting of C-C σ-bonds, in response to electrical stimuli, constitutes a promising strategy to construct complex organic skeletons. Here, we showcase how [ BuN][N] reacts with an isocyanide adduct of a tetrahedral and high-spin Ti complex, [(Tp )TiCl] (1), to enact N-atom transfer, C-N bond formation, and C-C coupling, to form a dinuclear complex, [(Tp )Ti{AdN(N)C-C(N)NAd}Ti(Tp )] (3), with two Ti ions bridged by a disubstituted oxalimidamide ligand ( Bu = -butyl, Tp = hydrotris(3--butyl-5-methylpyrazol-1-yl)borate, Ad = 1-adamantyl). Magnetic and computational studies reveal two magnetically isolated d Ti ions, and electrochemical studies unravel a reversible two-electron oxidation at -0.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
National Engineering Research Centre for Nanomedicine, College of Life Science and Technology, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.
Image-guided surgery plays a critical role in improving the cancer patient prognosis. However, current clinical probes are often single-modal with "always-on" signals, failing to provide complementary and precise guidance across all perioperative phases. To tackle this hurdle, we develop a biomarker-activatable, multimodal nanoprobe - - based on redox-mediated manganese valence switching for tumor-specific, perioperative image-guided surgery.
View Article and Find Full Text PDFNano Lett
September 2025
Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH), Pohang, 37673, Republic of Korea.
Active manipulation of terahertz (THz) waves is important for future optoelectronic applications, but most approaches rely on volatile or slow actuation, limiting efficiency and stability. Here, we report a nonvolatile, low-voltage tunable THz transmission device based on electrochemical modulation of a conductive polymer thin film integrated with metallic nanoresonators. A thin film of PEDOT:PSS, deposited via a single-step spin-coating process onto the nanoresonator array, enables efficient modulation of resonance-enhanced THz transmission with a gate voltage of less than 1 V.
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