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Magnesium alloys with a high volume fraction of secondary phases exhibit inferior formability. Therefore, investigating their thermal deformation characteristics is critical for optimizing thermal processing techniques. In this work, isothermal compression experiments were performed on a Mg-15Gd-8Y-6Al-0.3Mn alloy with an elastic modulus of 51.3 GPa with a substantial volume of aluminum-rare earth (AlRE) phases. The rheological behavior and microstructural evolution of the material were systematically investigated at varying temperatures (350-500 °C) and strain rates (0.001-1.000 s). The calculated thermal processing diagram indicates that the unstable region gradually enlarges with increased strain, and all unstable regions appear within the high-strain-rate, low-temperature domain. The ideal thermal processing range of the alloy is 350-500 °C at strain rates ranging from 0.001 to 0.016 s. Particle-stimulated nucleation and discontinuous dynamic recrystallization are both verified to be responsible for the recrystallized microstructure of the alloy. The recrystallized grains exhibit a relatively random crystallographic orientation. As recrystallization proceeds, the texture gradually transitions from a typical [0001] texture in the compression direction to a random texture accompanied by decreased texture intensity. This work sheds new light on the thermo-mechanical processing of high-modulus Mg alloys, which could help design suitable processing techniques for related materials.
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http://dx.doi.org/10.3390/ma17194784 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, 333 Long Teng Road, Shanghai 201620, P.R. China.
Silicon carbide (SiC) membranes combine exceptional chemical, thermal, and mechanical stability but suffer from surface inertness that precludes functionalization. Conversely, MOFs offer unmatched molecular selectivity but are typically powders, severely limiting their practical use. To address this, we develop a generalizable route to fabricate ultrastable MOF@SiC membranes via sequential oxidation and acidification, creating abundant Si-OH sites on SiC surfaces that covalently bond with Zr-MOF crystals; the bonding mechanism between MOFs and substrates has been extensively studied.
View Article and Find Full Text PDFSci Prog
September 2025
School of Mechanical and Automotive Engineering, Shanghai University of Engineering Science, Shanghai, China.
To address the growing demand for temperature control precision and uniformity in wafer processing, a specialized electrostatic chuck temperature control system based on thermal control coatings is proposed, aiming to enhance thermal management robustness and homogeneity. This study employs a zoned control methodology using metal-oxide conductive coatings on silicon carbide wafer heating plates. A quadrant-based thermal control coating model was established, and finite element analysis was conducted to compare temperature distribution characteristics across three geometric configurations: sectorial, spiral, and zoned designs.
View Article and Find Full Text PDFJ Chem Phys
September 2025
Center of Materials and Nanotechnologies (CEMNAT), Faculty of Chemical Technology, University of Pardubice, nam. Cs legii 565, 530 02 Pardubice, Czech Republic.
Joint direct microscopy-calorimetry measurements of crystal growth were performed for a 60 nm amorphous Sb2S3 film deposited either on a Kapton foil or on a soda-lime glass. Calorimetric crystallization proceeded in two steps, originating either from mechanical and stress-induced defects (230-275 °C) or from homogeneously formed nuclei (255-310 °C); both processes exhibited an identical activation energy of 200 kJ mol-1. At temperatures <230 °C, a Sb2O3 crystalline phase formed along the rhombohedral Sb2S3 structure.
View Article and Find Full Text PDFChemSusChem
September 2025
School of Chemical Sciences, Indian Institute of Technology Mandi, Mandi, 175005, Himachal Pradesh, India.
Accumulation of waste plastics on the earth's surface is a global challenge. There is a possibility of turning this challenge into an opportunity by plastic upcycling. In this work, the potential of bismuth oxychloride (BiOCl) as a heterogeneous catalyst for the glycolysis of polyethylene terephthalate (PET) is reported.
View Article and Find Full Text PDFFront Digit Health
August 2025
FEN - Graduate School in Engineering, State University of Rio de Janeiro (UERJ), Rio de Janeiro, Brazil.
Background: This paper presents the application of simulation to assess the functionality of a proposed Digital Twin (DT) architecture for immunisation services in primary healthcare centres. The solution is based on Industry 4.0 concepts and technologies, such as IoT, machine learning, and cloud computing, and adheres to the ISO 23247 standard.
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