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During the last glaciation, the northern hemisphere experienced profound millennial-scale changes (termed Dansgaard-Oeschger (DO) events) in atmospheric and oceanic temperatures. In the North Atlantic, the fluctuations resulted in extremely unstable bottom water conditions with bottom water temperatures (BWT) varying up to > 5 °C. We have studied these changes in a core from 1,300 m water depth at Vestnesa Ridge, northwestern Svalbard margin to investigate a possible connection between BWT and seepage of methane from the seafloor covering the period ~ 50-6 ka. Beneath Vestnesa Ridge, gas hydrates containing vast amounts of methane are kept stable due to the high pressure and low temperatures. Release of gas is shown by numerous pockmarks on the seafloor. The pockmarks at 1,300 m water depth are presently inactive, but they bear witness of earlier activity. Our study shows that from ~ 50-6 ka, the core site experienced repeated increases in BWT and in the emissions of gas, both following the pattern of the DO events. This correspondence in time scale indicates that BWT was the primary forcing factor for the variability in methane release. However, the releases were delayed by up to > 1,000 years compared to the initial increase in BWT.
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http://dx.doi.org/10.1038/s41598-024-72865-3 | DOI Listing |
Mar Pollut Bull
September 2025
School of Marine Sciences, Sun Yat-sen University, and Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Zhuhai 519082, China; The Research Center of Ocean Climate, Sun Yat-sen University, Zhuhai 519082, China; Pearl River Estuary Marine Ecosystem Research Station, Ministry of E
Estuarine plumes (EPs) are recognized as critical drivers of dissolved organic matter (DOM) heterogeneity in coastal zones, primarily by inducing phytoplankton blooms and subsequent bottom-water dissolved oxygen (DO) depletion. However, the specific mechanisms governing the EP-driven transformations of DOM molecular composition and biogeochemical fate remain elusive. Here, we integrated optical spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry to characterize the molecular signatures of DOM and their biogeochemical transformations within EP-influenced bottom waters of the Pearl River Estuary.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
The Affiliated Dongguan Songshan Lake Central Hospital, Guangdong Provincial Key Laboratory of Research and Development of Natural Drugs, School of Pharmacy, Guangdong Medical University, Dongguan, 523808, China.
This study explores the extraction of polysaccharides from Nostoc commune Vauch. using ultrasonic-assisted three-phase partitioning with deep eutectic solvents (UA-TPP-DES). Response surface methodology was used to determine the optimized UA-TPP-DES conditions as follows: a 1: 2 M ratio of lauric acid to terpineol, 30 min of ultrasonication at 60 °C with 100 W power, 20 % moisture content, 20 % w/w (NH)SO concentration, and a 2: 1 top-to-bottom phase volume ratio.
View Article and Find Full Text PDFEnviron Res
September 2025
Department of Environment and Energy, Sejong University, Seoul 05006, South Korea. Electronic address:
Identifying the sources of sedimentary organic matter (OM) is essential for understanding pollution dynamics and guiding effective management in estuarine environments. This study proposes a novel and transferable source tracking framework that integrates Fourier transform infrared (FTIR) and fluorescence spectroscopy with a principal component analysis-absolute principal component score-multiple linear regression (PCA-APCS-MLR) receptor model to apportion OM sources in surface sediments across four South Korean estuaries with contrasting land use. Five new infrared-based indices (IRIs), developed from diagnostic FTIR absorbance features of water-extractable organic matter (WEOM), were designed to capture source-specific functional group compositions linked to terrestrial, synthetic, and petroleum-derived OM.
View Article and Find Full Text PDFJ Chem Phys
September 2025
Department of Chemistry, Chicago Center for Theoretical Chemistry, Institute for Biophysical Dynamics, and James Franck Institute, The University of Chicago, 5735 S. Ellis Ave., SCL 123, Chicago, Illinois 60637, USA.
Molecular dynamics simulations are essential for studying complex molecular systems, but their high computational cost limits scalability. Coarse-grained (CG) models reduce this cost by simplifying the system, yet traditional approaches often fail to maintain dynamic consistency, compromising their reliability in kinetics-driven processes. Here, we introduce an adversarial training framework that aligns CG trajectory ensembles with all-atom (AA) reference dynamics, ensuring both thermodynamic and kinetic fidelity.
View Article and Find Full Text PDFThe DAGS bottom-up method employs water nanodroplets as 'templates' for the fabrication of diverse 1D polymeric nanostructures. Herein, we successfully applied this approach in the gas phase to obtain poly(ethyl cyanoacrylate) nanofibres (PECA-NF) with a diameter ranging from 137 to 721 nm. Their 1D growth was unveiled using energy-dispersive X-ray spectroscopy (EDX).
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