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The inferior mechanical performance and freeze-thaw (FT) resistance of recycled concrete are mostly due to the significant water absorption and porosity of recycled coarse particles. In this study, different dosages of zeolite powder were used in recycled concrete. A series of macroscopic tests were used to evaluate the workability and FT durability of zeolite powder-modified recycled concrete (ZPRC). X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to reveal the micro-mechanisms of FT resistance in ZPRC. The results show that the increase in zeolite powder content leads to a decrease in the slump and water absorption of ZPRC. Additionally, ZPRC with 10% zeolite powder has superior mechanical characteristics and tolerance to FT conditions. The higher strength and FT resistance of the ZPRC can be attributed to the particle-filling effect, water storage function, and pozzolanic reaction of zeolite powder, which results in a denser microstructure. The particle-filling effect of zeolite powder promotes the reduction of surface pores in recycled coarse aggregates (RCAs). The water storage function of zeolite powder can provide water for the secondary hydration of cement particles while reducing the free water content in ZPRC. The pozzolanic reaction of zeolite powder can also promote the generation of hydrated calcium silicate and anorthite, thereby making the microstructure of ZPRC more compact. These results provide theoretical guidance for the engineering application of recycled concrete in cold regions.
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http://dx.doi.org/10.3390/ma17112671 | DOI Listing |
Colloids Surf B Biointerfaces
December 2025
College of Life Sciences, Chongqing Normal University, No.37 Chengzhong Road, Shapingba District, Chongqing 401331, China. Electronic address:
The pervasive accumulation of tetracycline (TC) in aquatic ecosystems poses severe ecological and health threats, yet conventional technologies rarely achieve reliable removal under continuous-flow conditions. To overcome the intrinsic brittleness, aggregation and leaching of powdered ZIF-67, this study developed novel alginate-encapsulated MOF composite gel spheres (ALG/ZIF-67) via in-situ crystallization. This simple strategy generates hierarchical pores, anchors Co-N active sites and imparts mechanical robustness without sacrificing adsorption kinetics.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Division of Advanced Materials Engineering, Kongju National University, Budaedong 275, Seobuk-gu, Cheonan-si, Chungnam 31080, Republic of Korea; Center for Advanced Materials and Parts of Powder, Kongju National University, Cheonan-si, Chungnam 31080, Republic of Korea. Electronic address: hkchoi@ko
In this study, a hybrid nanocomposite (HNC) comprising MXene, ZIF-67, and chitosan was comprehensively evaluated for its structural, antibacterial, biocompatible, and cell migration properties. X-ray diffraction and Fourier transform infrared spectroscopy confirmed the successful integration of MXene, ZIF-67, and chitosan, with unique peaks suggesting the formation of a highly structured composite. Scanning and transmission electron microscopy revealed a uniform distribution of ZIF-67 on the MXene surface and subsequent decoration of the MXene/ZIF-67 surface with chitosan, which enhanced the structural complexity and surface roughness of the composite.
View Article and Find Full Text PDFMaterials (Basel)
July 2025
School of Architecture and Civil Engineering, Xihua University, Chengdu 610039, China.
Lithium slag (LS), a by-product of lithium extraction processes, poses a significant disposal challenge during the rapid development of new energy technologies. In this study, LS was used to replace partially washed sand in the process of mortar production to compensate for the content of stone powder in sand. Five mortar mixes containing varying proportions of LS were prepared, and the macroscopic performance was evaluated.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
August 2025
Department of Civil Engineering, Jaypee University of Information Technology, Waknaghat, Himachal Pradesh, India.
One of the major problems caused by the fast and unplanned growth of cities is the Urban Heat Island (UHI) effect. This happens when urban areas, especially pavements, become much hotter than the surrounding countryside, mainly during summer. The heat builds up on surfaces like roads and sidewalks because they absorb and store heat from the sun.
View Article and Find Full Text PDFChem Commun (Camb)
August 2025
Institute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany.
Iron exchanged zeolite catalysts have been synthesized by an aqueous ion-exchange using iron powder and acetic acid under a protective atmosphere. This simplified strategy for producing Fe(II) species was found to lead to highly dispersed iron even within the zeolite framework of small-pore zeolites, which is attractive for various catalytic applications. The obtained samples were used for the selective catalytic reduction of NO with NH.
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