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This in vitro study aimed to evaluate the additive manufacturing (AM) of cobalt chromium Co-Cr and titanium Ti alloy clasps for clinical use. After scanning the Ni-Cr die of the first molar, Akers' clasps were designed using computer-aided design/ computer-aided manufacturing (CAD/CAM). The clasps were manufactured from Co-Cr-W dental alloy and Ti-6Al-4V alloy powder using AM machines. Then, they were divided into two groups. The initial retentive force of the clasps was measured using a universal testing machine. Cyclic loading of the clasps was carried out by a specially designed insertion-removal testing apparatus in wet condition up to 5000 cycles. Retentive force was measured at 1000, 2000, 3000, 4000, and 5000 cycles. Moreover, the intaglio surface of each clasp was scanned using the scanner; and superimposition between the pre- and post-cycling clasp files was performed to evaluate deformation after cyclic loading. The fitting surfaces of retentive clasp tips were examined with a scanning electron microscope (SEM). Finally, it has been found that the initial retentive force for the Co-Cr group was 10.81 ± 0.37 N, and for the Ti group was 5.41 ± 0.18 N. Additionally, during the testing periods, both Co-Cr and Ti clasps continued to lose retentive force within the cycles of placement and removal. This effect was more prominent in the Co-Cr than in the Ti clasps. The distances between pre- and post-cycling in the retentive arm were -0.290 ± 0.11 mm and -0.004 ± 0.01 mm in Co-Cr and Ti alloys, respectively, and in the reciprocal arm were -0.072 ± 0.04 mm and -0.032 ± 0.04 mm in Co-Cr and Ti alloys, respectively. The retentive force required to remove the Ti clasps was found to be significantly lower than those required to dislodge the Co-Cr clasps. Co-Cr and Ti clasps lost significant amounts of retentive force from the initial use to the 3.5-year periods of simulated clinical use.
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http://dx.doi.org/10.1016/j.sdentj.2024.04.001 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, China.
Strong intermolecular interactions facilitate the formation of efficient ion transport channels, which, in turn, significantly boost the performance of anion exchange membranes (AEMs). Herein, 9-anthracene methanol with both π-π stacking and hydrogen bonding intermolecular forces is used as a bifunctional unit to synthesize high-performance AEMs through the Friedel-Crafts superacid catalytic reaction for the first time. The π-π stacking in the bifunctional units can induce hydrophilic pyridine cations to aggregate, and the hydrogen bonding can provide transport sites for OH and water molecules in the hydrophobic component.
View Article and Find Full Text PDFBarriers such as stigma and limited access to care continue to impede treatment for anxiety disorders. Telemedicine has emerged as a promising alternative to in-person psychological interventions, particularly after the COVID-19 pandemic. This systematic review compares the efficacy of telemedicine and in-person therapies for anxiety disorders, evaluating outcomes, patient engagement, and methodological rigor.
View Article and Find Full Text PDFMar Pollut Bull
September 2025
CSIR-National Institute of Oceanography, Dona Paula, Goa, 403004, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India.
The Indian Sundarban Delta (ISD), located at the confluence of the Ganga-Brahmaputra-Meghna river system along India's eastern coast, is among the world's most geomorphologically dynamic and environmentally vulnerable deltaic systems. Over the past five decades, the region has undergone substantial morphodynamic changes driven by natural forces such as relative sea-level rise, wave action, and sediment flux, as well as anthropogenic factors like upstream water regulation via dams and barrages. This study examines the long-term evolution of shoreline and island morphology across the ISD from 1972 to 2025 using multi-temporal Landsat datasets under consistent tidal conditions.
View Article and Find Full Text PDFArch Esp Urol
August 2025
Department of Urology, The Characteristic Medical Center of PLA Rocket Force, 100088 Beijing, China.
Background: We conducted a meta-analysis to compare the efficacy and drug-related adverse events (AEs) of the combination of tamsulosin and dutasteride versus tamsulosin monotherapy for the treatment of benign prostatic hyperplasia (BPH).
Methods: Relevant articles published in PubMed, Embase and Cochrane from 2004 to 2024 were searched and downloaded. These studies were screened following pre-established inclusion criteria, and data were extracted.
J Colloid Interface Sci
September 2025
Key Laboratory of Automobile Materials, Ministry of Education and School of Materials Science and Engineering, Jilin University, Changchun 130022, China. Electronic address:
Neither single electrolyte design nor solid electrolyte interface (SEI) engineering alone can effectively resolve the dual challenges of sluggish reaction kinetics and unstable interfaces in polymer-based lithium metal batteries (LMBs). Herein, a rational integrated design strategy is adopted to simultaneously fabricate poly(trifluoroethyl methacrylate-co-4-oxo-5,8,11-trioxa-3-azatridec-12-en-1-yl acrylate)-based gel polymer electrolyte (PTDA-GPE) and stable composite SEI during the thermal-induced in situ polymerization process. The resulting PTDA-GPE demonstrates superior Li transport kinetics (1.
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