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Article Abstract
The photocatalytic reduction of CO represents an environmentally friendly and sustainable approach for generating valuable chemicals. In this study, a thiophene-modified highly conjugated asymmetric covalent triazine framework (As-CTF-S) is developed for this purpose. Significantly, single-component intramolecular energy transfer can enhance the photogenerated charge separation, leading to the efficient conversion of CO to CO during photocatalysis. As a result, without the need for additional photosensitizers or organic sacrificial agents, As-CTF-S demonstrates the highest photocatalytic ability of 353.2 µmol g and achieves a selectivity of ≈99.95% within a 4 h period under visible light irradiation. This study provides molecular insights into the rational control of charge transfer pathways for high-efficiency CO photoreduction using single-component organic semiconductor catalysts.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11267385 | PMC |
| http://dx.doi.org/10.1002/advs.202402645 | DOI Listing |
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