Capture of CO during the Electrolysis Process and Its Utilization in Supercapacitor Materials.

With climate change and environmental issues, the emissions of CO and its greenhouse effect have become a focal point. At present, the utilization of CO includes its synthesis into chemicals and fuels such as methane, methanol, and CO. CO utilization can be achieved through carbon capture and storage technologies, which involve capturing CO from industrial emissions and storing it to reduce the CO concentration in the atmosphere. However, these CO capture and utilization technologies still face challenges, such as technical immaturity and high costs. One of the CO capture and utilization technologies is the production of energy storage materials. In this study, CO captured by molten salt was used as the carbon source, and TiO nanotube arrays were used as precursors. Titanium carbide nanotube arrays(TiC-NTAs)with high specific surface area and high conductivity were prepared by electrolysis. Afterward, the electrochemical energy storage performance of TiC in different electrolytes was tested. The results show that reducing the ionic radius of the electrolyte is conducive to increasing the area-specific capacitance of the device and that the degradation of the cycle life of the quasi-solid supercapacitor may be caused by an increase in the internal resistance due to the loss of water from the electrolyte. This study provides a reference value for the low-temperature synthesis of nanometal carbides and the selection of electrolytes.