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Article Abstract
By variation of the amount of GeO, two organic-inorganic hybrid germanoniobate frameworks with 6-connected and 10-connected topologies were constructed from peanut-shaped {α-GeNb} and {β-GeNb} clusters, respectively. The {α-GeNb} and {β-GeNb} clusters contain the most Ge centers of germanoniobates reported so far. The compounds exhibit proton conduction properties with a conductivity of 3.04 × 10 S·cm for and 1.62 × 10 S·cm for at 85 °C and 98% RH. The water vapor adsorption capacities for and are 5.86 and 4.40 mmol·g, respectively.
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| http://dx.doi.org/10.1021/acs.inorgchem.3c03905 | DOI Listing |
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Inorg Chem
January 2024
Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China.
By variation of the amount of GeO, two organic-inorganic hybrid germanoniobate frameworks with 6-connected and 10-connected topologies were constructed from peanut-shaped {α-GeNb} and {β-GeNb} clusters, respectively. The {α-GeNb} and {β-GeNb} clusters contain the most Ge centers of germanoniobates reported so far. The compounds exhibit proton conduction properties with a conductivity of 3.
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