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Laser-induced surface structuring is a promising method to suppress electron mulitpacting in the vacuum pipes of particle accelerators. Electrons are scattered inside the rough surface structure, resulting in a low Secondary Electron Yield (SEY) of the material. However, laser processing of internal pipe surfaces with a large aspect ratio is technologically challenging in terms of laser beam guidance and focusing. We present a 532 nm ultrashort-pulse laser setup to process the inner parts of 15 m long beam vacuum tubes of the Large Hadron Collider (LHC). Picosecond pulses at a repetition rate of 200 kHz are guided through an optical fiber toward an inchworm robot traveling inside the beam pipe. The system was installed, characterized, and tested for reliability. First surface treatments achieved the required scan precision. Cu2O-dominated nano-features were observed when processing at high average laser power (5 W) and slow scanning speed (5 mm s-1) in nitrogen flow, and the maximum SEY of copper was decreased from 2.1 to 0.7.
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http://dx.doi.org/10.1063/5.0166156 | DOI Listing |
Health Phys
September 2025
Nuclear and Radiological Engineering and Medical Physics Programs, George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA.
External exposure due to secondary photons (predominantly bremsstrahlung) generated from electron source emissions in environmental soil are of concern due to their ability to deposit significant amounts of ionizing energy to organs and tissues within the body. The "condensed history method" employed in many modern Monte Carlo (MC) codes may be used to simulate secondary photon yields (given as photons per beta decay) arising from electron source emissions with relatively few assumptions regarding the secondary photon spatial, energy, and angular dependencies. These yields may in turn be used to derive protection quantities such as secondary photon effective dose rate (DR) and risk coefficients for a variety of idealized external exposure scenarios.
View Article and Find Full Text PDFChemistry
September 2025
Research School of Chemistry, Australian National University, Canberra, ACT, 2610, Australia.
Multi-layered and orthogonal recognition is an excellent route to controlled molecular complexity. Here we report a series of heteroleptic complexes where two ligands pair together at a palladium(II) metal centre in complementary fashion and with orthogonality to others pairs. This complementarity is driven in part through hydrogen-bonding acceptor or donor sites proximal to the coordination domain (either DD:AA or AD:DA).
View Article and Find Full Text PDFBeilstein J Org Chem
August 2025
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, INEOS, Vavilova St. 28, Moscow, 119334, Russia.
Reducing agents with phosphorus-hydrogen bond, such as sodium hypophosphite, phosphite, and hypophosphorous acid are commercially available in bulk amounts, however, their usage is understudied in organic processes. While NaHPO has proved to be an efficient four-electron reductant in the catalyst-free reductive amination, the influence of cation in hypophosphite salt has not been studied yet. This issue is a fundamentally important factor.
View Article and Find Full Text PDFIndian J Nucl Med
August 2025
Department of Physics, Shi.C., Islamic Azad University, Shiraz, Iran.
Background: Another approach to improve the dose conformity is to use charged particles like protons instead of the conventional X- and γ-rays. Protons exhibit a specific depth-dose distribution which allows to achieve a more targeted dose deposition and a significant sparing of healthy tissue behind the tumor. In particular, proton therapy has, therefore, become a routinely prescribed treatment for tumors located close to sensitive structures.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA.
The fine-tuning of the (photo)physical properties of molecular photoswitches remains an active area of research, and recently, the incorporation of heterocycles into photoswitch scaffolds has emerged as an effective strategy in this vein. To assess the influence that heterocyclic rings have on hydrazone-based systems, we synthesized a series of photoswitches and examined the impact that heterocycles have on the switching efficiency. TD-DFT calculations and structure-property analyses revealed that heterocycles with basic nitrogen and secondary hydrogen-bonding sites (e.
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