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Two-dimensional chiral metasurfaces seem to contradict Lord Kelvin's geometric definition of chirality since they can be made to coincide by performing rotational operations. Nevertheless, most planar chiral metasurface designs often use complex meta-atom shapes to create flat versions of three-dimensional helices, although the visual appearance does not improve their chiroptical response but complicates their optimization and fabrication due to the resulting large parameter space. Here we present one of the geometrically simplest two-dimensional chiral metasurface platforms consisting of achiral dielectric rods arranged in a square lattice. Chirality is created by rotating the individual meta-atoms, making their arrangement chiral and leading to chiroptical responses that are stronger or comparable to more complex designs. We show that resonances depending on the arrangement are robust against geometric variations and behave similarly in experiments and simulations. Finally, we explain the origin of chirality and behavior of our platform by simple considerations of the geometric asymmetry and gap size.
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http://dx.doi.org/10.1021/acs.nanolett.3c02168 | DOI Listing |
Nanoscale
September 2025
St. Petersburg State University, 199034 St. Petersburg, Russia.
Using angle-resolved photoemission spectroscopy (ARPES) with spin resolution, scanning tunneling microscopy/spectroscopy (STM/STS) and density functional theory (DFT) methods, we study the electronic structure of graphene-covered and bare Au/Co(0001) systems and reveal intriguing features, arising from the ferrimagnetic order in graphene and the underlying gold monolayer. In particular, a spin-polarized Dirac-cone-like state, intrinsically related to the induced magnetization of Au, was discovered at point. We have obtained a good agreement between experiment and theory for bare and graphene-covered Au/Co(0001) and have proven that both Au ferrimagnetism and the Dirac-cone-like band are intimately linked to the triangular loop dislocations present at the Au/Co interface.
View Article and Find Full Text PDFNat Commun
September 2025
Institute for Theoretical Physics, University of Regensburg, Regensburg, Germany.
The nature of the dominant pairing mechanism in some two-dimensional transition metal dichalcogenides is still debated. Focusing on monolayer 1H-NbSe, we show that superconductivity can be induced by the Coulomb interaction when accounting for screening effects on the trigonal lattice with multiple orbitals. Using ab initio based tight-binding parametrizations for the relevant low-energy d-bands, we evaluate the screened interaction microscopically.
View Article and Find Full Text PDFSci Adv
September 2025
Materials Department, University of California, Santa Barbara, CA 93106-5050, USA.
Thermoelectric responses in two-dimensional electron gases subjected to magnetic fields have the potential to provide unique information about quasiparticle statistics. In this study, we show that chiral edge states play a key role in thermoelectric Hall bar measurements by completely controlling the direction of the internal thermal gradient. To this end, we perform measurements of the magnetothermoelectric responses of cadmium arsenide quantum wells.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
State Key Laboratory of Functional Crystals and Devices, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P.R. China.
Chiral metal halide perovskites (CMHPs) are a promising class of chiroptical materials with significant potential applications in chiral-optoelectronic and chiral-spintronic devices. However, their chirality induction generally stems from the incorporation of chiral ligands, which constitutes compositional diversity and functional versatility. Herein, we report a significant chiral expression resulting from two distinct mechanisms: chirality transfer induced by chiral organic cations and mirror symmetry breaking driven by stereochemically active lone pairs, both contributing to controlled chirality induction.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; Collaborative Innovation Center of Chemistry Science and Engineering, Tianjin 300072, China. Electronic address:
This work applies cellulose-based nanofilm as the platform to design a kind of stretching-responsive circularly polarized luminescence (CPL) material. Hierarchical structure photonic crystal material is prepared through the co-assembly of cellulose nanocrystals (CNCs) and poly(vinyl alcohol) (PVA) additive. By optimizing the amounts of PVA, the composite film presents high tensile strength (61.
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