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This part proposes a model of time-dependent diffuse photon remission for the center-illuminated-area-detection (CIAD) geometry, by virtue of area integration of the radially resolved time-dependent diffuse photon remission formulated with the master-slave dual-source scheme demonstrated in Part I for steady-state measurements. The time-domain model is assessed against Monte Carlo (MC) simulations limiting to only the Heyney-Greenstein scattering phase function for CIAD of physical scales and medium properties relevant to single-fiber reflectance (SfR) and over a 2 ns duration, in compliance with the timespan of the only experimental report of SfR demonstrated with a 50 µm gradient index fiber. The time-domain model-MC assessments are carried out for an absorption coefficient ranging three orders of magnitude over [0.001,0.01,0.1,1] at a fixed scattering, and a reduced scattering coefficient ranging three orders of magnitude over [0.01,0.1,1,10] at a fixed absorption, among others. Photons of shorter and longer propagation times, relative to the diameter of the area of collection, respond differently to the scattering and absorption changes. Limited comparisons of MC between CIAD and a top-hat geometry as the idealization of SfR reveal that the time-domain photon remissions of the two geometries differ appreciably in only the early arriving photons.
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http://dx.doi.org/10.1364/AO.478322 | DOI Listing |
Chem Rev
September 2025
Department of Physics, State Key Laboratory of Surface Physics, Fudan University, Shanghai 200438, P. R. China.
Diffusion is a fundamental process in the transfer of mass and energy. Diffusion metamaterials, a class of engineered materials with distinctive properties, enable precise control and manipulation of diffusion processes. Meanwhile, topology, a branch of mathematics, has attracted growing interest within the condensed matter physics community.
View Article and Find Full Text PDFAdv Healthc Mater
September 2025
Department of Mechanical Engineering, University of Arkansas, Fayetteville, AR, 72701, USA.
3D scaffold architecture is critical for directing human neural stem cell (hNSC) fate and spatial organization. In this study, two-photon lithography (TPL) is used to fabricate microcapillary scaffolds based on the Hilbert space-filling curve as biomimetic basement membrane structures for guiding hippocampal-derived hNSC differentiation. The scaffolds feature 80 µm lumens with porous ellipsoidal membranes suspended above the substrate to provide topographical cues and permit nutrient diffusion while maintaining mechanical stability.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Department of Materials Chemistry, National Institute of Chemistry, Ljubljana 1000, Slovenia.
The electrochemical CO reduction (ECOR) on copper (Cu) remains one of the most promising pathways to convert CO into value-added products. However, it suffers from severe restructuring, resulting in the unknown structural identity of the ECOR active catalyst. Here, we show that dissolution-redeposition is the universal early-stage restructuring mechanism in ECOR, occurring across all the tested Cu morphologies, including foils, nanoparticles, oxide-derived films, and gas diffusion electrodes.
View Article and Find Full Text PDFRadiologie (Heidelb)
September 2025
Institut für Diagnostische und Interventionelle Radiologie, Universitätsspital Zürich, Rämistrasse 100, 8091, Zürich, Schweiz.
Background: Pulmonary manifestations of systemic diseases represent a complex and diagnostically challenging field. While pulmonary involvement in immunological and hematological disorders is well described, lung involvement in rare genetic and congenital systemic diseases-such as systemic storage diseases, neuromuscular disorders, and phacomatoses-is only gradually gaining increased attention in radiological diagnostics.
Results: The pulmonary component often manifests secondarily, frequently after years of progression and worsening of the underlying disease.
Angew Chem Int Ed Engl
September 2025
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
The electrocatalytic acetylene semi-hydrogenation (EASH) driven by renewable energy offers an important non-petroleum route for ethylene production, yet suffers from insufficient reaction rate, ethylene selectivity, and energy efficiency. While tailoring catalytically active structures is effective for improving the EASH performance, the effects of mass transport at the mesoscale are poorly understood. Here, we show quantitatively the crucial role of interparticle mass transport within the catalyst layer of a gas diffusion electrode.
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