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We investigated the interfacial electronic structure of the bidimensional interface of single-layer graphene on a germanium substrate. The procedure followed a well-established approach using ultraviolet (UPS) and X-ray (XPS) photoelectron spectroscopy. The direct synthesis of the single-layer graphene on the surface of (110) undoped Ge substrates was conducted via chemical vapor deposition (CVD). The main graphitic properties of the systems were identified, and it was shown that the Ge substrate affected the electronic structure of the single-layer graphene, indicating the electronic coupling between the graphene and the Ge substrate. Furthermore, the relevant features associated with the Schottky contact's nature, the energy level's alignments, and the energy barrier's heights for electron and hole injection were obtained in this work. The results are useful, given the possible integration of single-layer graphene on a Ge substrate with the complementary metal-oxide-semiconductor (CMOS) technology.
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http://dx.doi.org/10.3390/nano13152166 | DOI Listing |
J Phys Chem B
September 2025
National Key Laboratory of Solid Rocket Propulsion, Northwestern Polytechnical University, Xi'an 710072, China.
Hexaazaisowurtzitane (CL-20) is a high-energy-density compound with poor thermal stability, which hinders its application in composite energetic systems. A bi-interface structure of polydopamine-coated graphene oxide (GO@PDA) is shown to markedly improve thermal stability compared with pristine CL-20 and single-layer coatings. Reactive molecular dynamics simulations enhanced by a neural network potential (NNP) reveal that the delayed onset of decomposition arises from suppressed NO release and altered spatial density distribution, while interfacial -OH and -COOH groups consume intermediates, redirect decomposition pathways, and inhibit autocatalytic chain reactions.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634, United States.
Developing next-generation anodes with high silicon (Si) contents requires thoughtful embedment of Si particles in protective media, mainly carbonaceous materials. However, it has been challenging to simultaneously realize optimal electrical conduction, structural integrity, and low-cost synthesis for advancing Si-carbon materials. In this work, we addressed these challenges by synthesizing a composite, where commercial Si nanoparticles are embedded in a dual carbon framework via a facile solution mixing and annealing process.
View Article and Find Full Text PDFNanoscale
August 2025
Dpto. Física de la Materia Condensada, Universidad Autónoma de Madrid, c/Francisco Tomás y Valiente 7, 28049 Madrid, Spain.
Two-dimensional (2D) van der Waals (vdW) antiferromagnets (AFMs) have emerged as promising candidates for spintronic applications due to their fast spin dynamics and robustness against external magnetic perturbations. However, their intrinsically low electrical conductivity challenges their integration into electronic devices. A possible path to overcome this limitation is to form vdW heterostructures with highly conductive materials such as graphene, which can sensitively respond to interfacial magnetic interactions.
View Article and Find Full Text PDFBioresour Technol
August 2025
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006 Hunan, China. Electronic address:
Achieving both high activity and good stability remains a challenge for the design of MoS-based catalysts in the hydrodeoxygenation (HDO) reaction. Herein, a robust catalyst with single-layer CoMoS anchored on hydrophobic reduced graphene oxide (SL-CoMoS/rGO) was fabricated, which exhibited high activity, selectivity and excellent stability in the HDO of lignin-derived phenolics to arenes. Utilizing the HDO of 4-methylphenol as a probe reaction, the catalyst afforded a conversion of 98.
View Article and Find Full Text PDFLangmuir
September 2025
School of Mechanical and Electrical Engineering, Guangzhou University, Guangzhou 510006, China.
The relationship between adhesion force and contact time remains poorly understood and warrants further investigation. The effect of the number of graphene layers on the adhesion force at the silica interface remains unclear. To address this, an experimental investigation was conducted.
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