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Article Abstract
A newly binuclear nickel(II) complex, [Ni(en)(ox)](ClO) () (where en = ethylenediamine, and ox = oxalate), has been isolated from a reaction of NiCl·6HO, ethylenediamine, ammonium oxalate and sodium perchlorate in water and its crystal structure has been determined by X-ray crystallography and infra-red techniques. Compound was successfully employed to promote the one-pot reaction of aldehydes, amines and acetylenes for the construction of corresponding propargylamines under solvent-free media with fine yields. Further studies reveal this catalytic system can be refreshed and used again in five runs.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10395144 | PMC |
| http://dx.doi.org/10.1016/j.heliyon.2023.e17743 | DOI Listing |
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