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Article Abstract
Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (HTCBPA) gives rise to a new thorium-based metal-organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(VI) anions.
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A robust thorium-organic framework as a bifunctional platform for iodine adsorption and Cr(VI) sensitization.
Dalton Trans
January 2023
School of Nuclear Science and Technology, Xi'an Jiaotong University, Xi'an, 710049, P. R. China.
Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (HTCBPA) gives rise to a new thorium-based metal-organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(VI) anions.
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