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Article Abstract
Homo-valent diruthenium(II,II) carbonates have been underexplored hitherto. This paper reports the synthesis and crystal structure of a diruthenium(II,II) compound, NaRu(CO)·10HO (1). It has a two-dimensional structure in which the paddle-wheel diruthenium units of Ru(CO) are cross-linked through the carbonate groups. The investigation of the primary magnetic properties and theoretical studies with density functional theory (DFT) reveal that weak antiferromagnetic interactions are propagated between the Ru units which contain two unpaired electrons in an electron configuration σπδπ*δ* with a ground state = 1. According to Raman spectrum measurements combined with theoretical calculations, the strong peak at 356 cm in the small-wavenumber region was assigned to the stretching of the Ru-Ru double bonds.
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