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http://dx.doi.org/10.1021/acssynbio.2c00656 | DOI Listing |
Plast Reconstr Surg
September 2025
Department of Plastic and Reconstructive Surgery, Kangnam Sacred Heart Hospital, Hallym University College of Medicine, 1 Singil-ro, Yeongdeungpo-gu, Seoul, Republic of Korea 07441.
Background: The insertion of implants and tip plasties has been performed in Asian patients for an attractive and higher nasal profile, which can result in diverse tip deformations such as notching, pinching, alar retraction, incompetent external valve, deviated tip, cephalic rotation, and lateral crus malposition due to inappropriate manipulation of the lower lateral cartilage and/or silicone capsular contracture. This study aimed to investigate the effectiveness and utility of applying lateral crural strut graft (LCSG) as a consistent and appropriate surgical method to correct various nasal tip deformities that occur as complications following rhinoplasty in Asian patients.
Methods: We prospectively studied 37 patients with a minimum follow-up of 12 months among 53 patients who underwent secondary rhinoplasty, including LCSG, between January 2016 and December 2020.
Adv Colloid Interface Sci
August 2025
Cracow University of Technology, Faculty of Chemical Engineering and Technology, Department of Biotechnology and Physical Chemistry, Warszawska 24, 31-155 Cracow, Poland; Photo4Chem, Lea 114, 30-133 Cracow, Poland; Photo HiTech Ltd., Bobrzyskiego 14, 30-348 Cracow, Poland. Electronic address: joanna
Silatranization, a specialized variant of silanization using silatrane compounds, is emerging as a powerful strategy to functionalize material surfaces. Compared to conventional silane coupling agents, silatranes exhibit remarkable hydrolytic stability and enhanced resistance to self-condensation, enabling controllable, water-independent formation of a polysiloxane self-assembled monolayer. This review critically examines the unique structure of silatranyl cages, emphasizing how the intramolecular N->Si bond and chelate effect modulate the silicon center's reactivity toward hydroxyl-decorated surfaces.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Hunan Joint International Research Center for Carbon Dioxide Resource Utilization, School of Physics, Central South University, Changsha, Hunan 410083, China.
Single-atom Ni catalysts hold great promise for the acidic CO reduction reaction (CORR), owing to their high CO selectivity. However, their performance under industrially relevant high current conditions is limited by the weak interaction between isolated Ni-N sites and *COOH intermediates, restricting efficient CO conversion. Here, we introduced edge-rich Ni-N sites via support vacancy engineering to enhance *COOH adsorption, thereby boosting the CORR activity and selectivity in acidic media.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
Nantes Université, CNRS, CEISAM UMR 6230, F-44000 Nantes, France.
Owing to their unique combination of magnetic and optical properties, luminescent polychlorinated radicals are promising candidates for advanced applications in both optoelectronics and quantum technologies. In this study, we employ the lineshape formalism within a computational protocol based on time-dependent density functional theory (TD-DFT) to investigate the excited-state properties of six representative members of this family presenting different sizes and excited-state characters. We explore a wide range of density functionals, applying or not the Tamm-Dancoff approximation (TDA), combined with different vibronic models, namely, the vertical gradient (VG), vertical Hessian (VH), and adiabatic Hessian (AH), as well as dipole moment expansions using the Franck-Condon (FC) and Herzberg-Teller (HT) approximations.
View Article and Find Full Text PDFNature
September 2025
Department of Orthopaedics, University Medical Centre Utrecht, Utrecht University, Utrecht, The Netherlands.
We introduce Generative, Adaptive, Context-Aware 3D Printing (GRACE), a new approach combining 3D imaging, computer vision and parametric modelling to create tailored, context-aware geometries using volumetric additive manufacturing. GRACE rapidly and automatically generates complex structures capable of conforming directly around features ranging from cellular to macroscopic scales with minimal user intervention. Here we demonstrate its versatility in applications ranging from synthetic objects to biofabrication, including adaptive vascular-like geometries around cell-laden bioinks, resulting in improved functionality.
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