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The carbon footprint reduction mandate and other eco-friendly policies currently in place are constantly driving the trend of the synthesis and application of sustainable functional materials. The bitumen industry is not an exception to this trend and, every day, new technologies that facilitate safer, cost effective and more sustainable industrial processes and road paving operations are being researched and brought to light. A lot of research is currently ongoing to improve bitumen's properties due to its use as a binder in road paving processes. Over the years, the most common method to improve bitumen's properties has been with the use of additives. The major drawback in the use of these additives is the fact that they are substances of strong chemical nature which are either too acidic, too basic or emit toxic fumes and volatile organic compounds into the environment. In the long run, these chemicals are also toxic to the road pavement personnel that carry out the day to day industrial and paving operations. This led researchers to the initiative of synthesizing and applying biomaterials to be used as additives for bitumen. In this light, several studies have investigated the use of substances such as bio-oils, natural waxes, gum, polysaccharides and natural rubber. This literature review is aimed at classifying the different bio-based materials used to improve bitumen's properties and to provide a deeper knowledge of the application of these biomaterials in bitumen technology. In general, we highlight how the research efforts elaborated herein could potentially foster safer, sustainable, eco-friendly approaches to improving bitumen's properties while also promoting a circular economy.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9783757 | PMC |
http://dx.doi.org/10.3390/molecules27248826 | DOI Listing |
MethodsX
December 2025
Delft University of Technology, Delft, the Netherlands.
Previous work demonstrated that Random Forest Regressors (RFRs) could estimate the physical properties of bitumen using molecular descriptors derived from Molecular Dynamics (MD) simulations, thereby reducing the need for computationally intensive simulations. However, due to their decision-tree structure, RFRs lack true predictive capabilities, particularly for interpolation and extrapolation beyond the training data. This study advances that foundation by employing Artificial Neural Networks (ANNs), which-when properly trained-can capture complex relationships with greater continuity and generalizability.
View Article and Find Full Text PDFMaterials (Basel)
August 2025
Department of Theoretical and Applied Sciences, Università degli Studi eCampus, 22060 Novedrate, Italy.
Several variables influence the performance of hot asphalt mixtures including reclaimed asphalt pavement (RAP). Among these, the virgin bitumen's origin, the mix production temperature and the time the mix is kept at a high temperature between mixing and compaction play a fundamental role but are often neglected. This study aimed to quantify the negative effects associated with the improper choice of these variables.
View Article and Find Full Text PDFNanomaterials (Basel)
July 2025
Sustainable Asphalt Research Group, School of Civil Engineering, Universiti Sains Malaysia (Engineering Campus), Nibong Tebal 14300, Pulau Pinang, Malaysia.
This research evaluates the rheological and mechanical properties of polymer- and nanomaterials-modified bitumen by incorporating nanosilica (NSA), nanoclay (NCY), and Acrylonitrile Styrene Acrylate (ASA) at 5% by weight of the bitumen. The samples were prepared at 165 °C for one hour to obtain homogeneous blends. All samples were subjected to short- and long-term aging to simulate the effects of different operating conditions.
View Article and Find Full Text PDFSci Rep
July 2025
Department of Civil Engineering, University of Guilan, Rasht, Iran.
Surface contaminants on pavements, combined with road runoff, can alter the pH of water infiltrating the asphalt concrete (AC), which weakens the mixture's resistance to failures such as fatigue cracking. To address this, we evaluated the potential of calcined dolomite powder for enhancing moisture resistance in asphalt mixtures by adding it to bitumen at 0.5% and 1% by weight.
View Article and Find Full Text PDFSci Rep
July 2025
Associate Professor, Department of Civil Engineering, Faculty of Engineering, University of Bojnord, Bojnord, Iran.
Hot-mix asphalt (HMA) fatigue cracking is governed by external factors, including temperature, precipitation, and traffic loading, alongside internal factors, such as bitumen type, bitumen percent, air void, and the aggregate's mineralogy and physical properties. As a critical external factor, moisture, particularly runoff with varying acidity, exacerbates fatigue cracking through physical and chemical interactions. The use of advanced additives such as nanomaterials in HMAs enhances their performance against various types of distress.
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