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A host-guest interaction activated Bobbitt oxidant for highly efficient oxidation of alcohols. | LitMetric
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A host-guest interaction activated Bobbitt oxidant for highly efficient oxidation of alcohols.

Jinyang Wu , Youran Luo , Lingxuan Chen , Xuan Sun , Xinnan Chen , Song Qin , Wen Feng , Xiaowei Li , Lihua Yuan

Chem Commun (Camb)

Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, College of Chemistry, Sichuan University, Chengdu, 610064, China.

Published: November 2022

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Article Abstract

Host-guest complexation using hydrogen-bonded macrocycles was found to enable activation of the Bobbitt oxidant reagent, which greatly facilitates the highly efficient oxidation of unactivated primary alcohols. This work provides a complementary approach to the activation of Bobbitt's salt with shape-persistent macrocycles in supramolecular catalysis.

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http://dx.doi.org/10.1039/d2cc05027gDOI Listing

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