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Stereoselective β-Mannosylation via Anomeric -Alkylation with L-Sugar-Derived Electrophiles. | LitMetric
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Stereoselective β-Mannosylation via Anomeric -Alkylation with L-Sugar-Derived Electrophiles.

Ishani Lakshika Hettiarachchi , Shuai Meng , Mira Chahine , Xiaohua Li , Jianglong Zhu

European J Org Chem

Department of Chemistry and Biochemistry and School of Green Chemistry and Engineering, The University of Toledo, 2801 W. Bancroft Street, Toledo, Ohio 43606, United States. https://www.utoledo.edu/nsm/chemistry/people/Webpages/Zhu.html.

Published: December 2021

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Article Abstract

A total synthesis of the trisaccharide repeat unit of serogroup E1 -antigen is reported. This synthesis features a key β-mannosylation reaction via cesium carbonate-mediated anomeric -alkylation of a partially protected D-mannose with an L-fucose-derived electrophile for the first time.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9389860PMC
http://dx.doi.org/10.1002/ejoc.202100903DOI Listing

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