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In the electrocoagulation process, passivation or corrosion of the electrodes is one of the biggest challenges that cause a drop in treatment effectiveness. In this study, the effect of polarity switching was investigated, for the first time, in an attempt to enhance electrocoagulation treatment's ability to remove chemical oxygen demand (COD) and color from pretreated landfill leachate. Moreover, the ratio of the anode to cathode surface area and rotating electrode were examined in light of experimental results. The effect of different parameters, including the stirring speed, initial leachate pH, electrical current density, anode to cathode surface area ratio, and polarity switching time on system efficiency, was evaluated using the one-factor-at-a-time (OFAT) classical method. According to the results, polarity switching resulted in an almost 18% increase in COD removal, 14% increase in color removal, 13% decrease in electrical energy consumption (EEC), 51% decrease in the specific sludge production (TSS/COD), and improved electrode performance compared to non-polarity switching mode. The findings of this research showed the highest COD and color removal efficiencies, which were 34% and 67%, respectively, in a 120 min period, a stirring speed of 135 rpm, the initial leachate pH of 9, the current density of 14.4 mA/cm, the anode/cathode surface ratio of 0.35, and the polarity switching time of 300 s.
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http://dx.doi.org/10.1016/j.jenvman.2022.115733 | DOI Listing |
Phys Rev Lett
August 2025
Huazhong University of Science and Technology, Wuhan National Laboratory for Optoelectronics and School of Physics, Wuhan 430074, China.
We propose a scheme for retrieving the ultrafast valley polarization (VP) dynamics in two-dimensional hexagonal materials via attosecond circular dichroism (CD) transient absorption spectroscopy. This approach builds on the CD transition between the first and higher conduction bands induced by the circularly polarized probe pulses. The population imbalance at nonequivalent valleys in the first conduction band is proportionally mapped onto the difference in absorption coefficients of two probe pulses with opposite helicities, supporting an unprecedented quantitative retrieval of the corresponding VP dynamics with subfemtosecond time resolution.
View Article and Find Full Text PDFPhys Rev Lett
August 2025
Nanjing University of Aeronautics and Astronautics, State Key Laboratory of Mechanics and Control for Aerospace Structures and Key Laboratory for Intelligent Nano Materials and Devices of the Ministry of Education, Institute of Nano Science, Nanjing, 210016, China.
Multistate ferroelectric polarization holds promise for realizing high-density nonvolatile memory devices, but so far is restricted to a few traditional ferroelectrics. Here, we show that nanoconfined two-dimensional (2D) ferroelectric ice can achieve phase-dependent multistate polarization through extensive classical and ab initio molecular dynamics simulations. An in-plane electric field is found to induce the reversible transition between a low-polarization AA-stacked hexagonal ice phase and an unprecedented high-polarization AB-stacked ice phase, resulting in a four-state ferroelectric switching pathway.
View Article and Find Full Text PDFPhys Rev Lett
August 2025
Universität Innsbruck, Institut für Experimentalphysik, Technikerstrasse 25, 6020 Innsbruck, Austria.
Establishing networks of quantum processors offers a path to scalable quantum computing and applications in communication and sensing. This requires first developing efficient interfaces between photons and multiqubit registers. In this Letter, we show how to entangle each individual matter qubit in a register of ten to a separate traveling photon.
View Article and Find Full Text PDFBioessays
September 2025
MY Small G Protein Research Group, Bioprocess Technology Division, School of Industrial Technology, Universiti Sains Malaysia, Pulau Pinang, Malaysia.
Advanced biosensing technologies, such as Förster resonance energy transfer (FRET) and bioluminescence resonance energy transfer (BRET), have enabled real-time, high-resolution tracking of Rho GTPase activity, surpassing traditional methods like pull-down assays. However, current biosensors mainly detect the GTP-bound active state through effector interactions, without directly measuring Rho GTPase expression or identifying related biomarkers of abnormal activation. Small Rho GTPases are essential molecular switches that regulate key cellular processes such as cytoskeletal organization, cell movement, polarity, vesicle trafficking, and the cell cycle.
View Article and Find Full Text PDFDalton Trans
September 2025
Department of Chemistry & Biochemistry, University of Maryland Baltimore County, Baltimore, MD 21250, USA.
Two-dimensional van der Waals (2D-vdW) semiconducting ferroelectrics, such as CuInPSe (CIPSe) and CuInPS (CIPS), offer unique opportunities for lightweight, scalable, low-power nanoscale electronic devices. However, the limited pool of functional 2D-vdW ferroics highlights the need for clear design principles that can be used to guide experiments. Here, we use first-principles density functional theory (DFT) to study how isovalent atomistic substitution at In and P sites modifies structure, polarization, and electronic properties in CIPSe and CIPS.
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