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The interaction between surface water and groundwater constitutes a critical process to understand the quantitative and qualitative regime of dependent hydrosystems. A multi-scale approach combining cross-disciplinary techniques can considerably reduce uncertainties and provide an optimal understanding of groundwater and surface water exchanges. The simulation process constitutes the most effective tool for such analysis; however, its implementation requires a variety of data, a detailed analysis of the hydrosystem, and time to finalize a reliable solution. The results of the simulation process contribute to the raising of awareness for water protection and the application of better management strategies. Knowledge of models' parameters has great importance to ensure reliable results in the modeling process. In this study, a literature overview of modeling applications in groundwater - surface water interaction is provided. In this context, a comprehensive and holistic approach to groundwater and surface water simulation codes is here presented; results, case studies, and future challenges are also discussed. The main finding of the analysis highlights uncertainties and gaps in the modeling process due to the lack of high frequency and depth dependent field measurements. In many studies, authors underestimate the importance of the hydrogeological regime, and the discretization of hydraulic parameters is often lumped in a simplified manner. The modeling ethics in terms of data transparency and openness should be widely considered to improve the modeling results. The current study contributes to overcome common weaknesses of model applications, fulfils gaps in the existing literature, and highlights the importance of the modeling process in planning sustainable management of water resources.
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http://dx.doi.org/10.1016/j.scitotenv.2022.157355 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
School of Biomedical Engineering, Shenzhen University Medical School, Shenzhen University, Shenzhen, Guangdong518055, China.
The rapid development of liquid exfoliation technology has boosted fundamental research and applications of ultrathin two-dimensional (2D) materials. However, the small-sized exfoliated 2D materials with a high specific surface area may exhibit poor chemical stability. Understanding the stability of 2D crystals will be significant for their preservation and service and for the development of new stable phases via the spontaneous transition from unstable structures.
View Article and Find Full Text PDFMater Horiz
September 2025
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
Dispersing iridium onto high-specific-surface-area supports is a widely adopted strategy to maximize iridium utilization in anode catalysts of proton exchange membrane water electrolysis (PEMWE). However, here we demonstrate that the overall cell performance, including initial efficiency and long-term stability, does not benefit from the typical high specific surface area of catalyst supports. The conventional understanding that high iridium utilization on high-specific-surface-area supports increases activity holds only in aqueous electrolytes, while under the typical working conditions of PEMWE, the mass transport within the anode catalyst layers plays a more significant role in the overall performance.
View Article and Find Full Text PDFDalton Trans
September 2025
Instituto de Química, Universidad Nacional Autónoma de México, Circuito Interior, CU, Ciudad de México, 04510, Mexico.
Synthesis, characterization, and electrocatalytic water oxidation studies of the cubane-type complexes [(μ-)CoCl(MeOH)] (1) and [(μ-)CoCl(MeOH)] (2) are herein reported. Cubanes 1 and 2 were obtained in high yields under mild conditions by self-assembly of the ligands = 1--2-benzimidazolylmethanol and = 1-methyl-2-benzimidazolylmethanol with CoCl·6HO in basic methanolic solution. Both compounds feature a cubane-type structure in which the central {CoO} units are built by four Co centers coordinated by alkoxide-bridged oxygen and nitrogen atoms from the deprotonated ligands and stabilized by MeOH molecules and chloride ions.
View Article and Find Full Text PDFTurk J Pharm Sci
September 2025
Chandigarh College of Pharmacy, Chandigarh Group of Colleges, Landran, Punjab.
Objectives: Lycopene is a powerful antioxidant with diverse health benefits. However, it belongs to the Biopharmaceutics Classification System II; thus, it depicts poor water solubility and dissolution. Its lipophilic nature hinders the bioavailability of this drug.
View Article and Find Full Text PDFWater Res
August 2025
Guangzhou Landscape Architecture Group Co., Ltd., Guangzhou 510000, PR China; Guangzhou Municipal Construction Group Co., Ltd., Guangzhou 510030, PR China.
Enhanced ammonium (10.6 - 14.7%) and total inorganic nitrogen (TIN, 4.
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