Lignosulfonate valorization into a Cu-containing magnetically recyclable photocatalyst for treating wastewater pollutants in aqueous media.

This study presents an eco-friendly and economical process for preparing a magnetic copper complex conjugated to modified calcium lignosulfonate (LS) through a diamine (FeO@LS@naphthalene-1,5-diamine@copper complex; FLN-Cu) as a green and novel catalyst. The prepared catalyst was characterized by Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), Brunauer-Emmett-Teller (BET), energy-dispersive X-ray spectroscopy (EDS), elemental mapping, inductively coupled plasma-optical emission spectrometry (ICP-OES) and field emission scanning electron microscopy (FESEM) techniques. The photocatalytic performance of the synthesized FLN-Cu catalyst was investigated by the degradation of aqueous solutions of dyes such as Rhodamine B (RhB), methylene blue (MB), and Congo red (CR) under UV irradiation. The dye degradation was followed by UV-Vis (ultraviolet-visible) spectrophotometry by measuring the changes in absorbance. The effects of different factors such as pH, contact time, photocatalyst dosage, and initial concentration of dye on the adsorption percentage were also investigated. Moreover, the catalyst showed high stability and could be readily separated from the reaction media using a magnet and reused five times without a remarkable loss of catalytic ability.